caa a22 4500 477080758 CHVBK 20180405111449.0 cr unu---uuuuu 170330e19960801xx s 000 0 eng 10.1007/BF02113856 doi (NATIONALLICENCE)springer-10.1007/BF02113856 CO2 reforming and partial oxidation of methane [Elektronische Daten] [H. Papp, P. Schuler, Q. Zhuang] CO2 reforming and partial oxidation of CH4 were investigated on different supported noble metal and Ni catalysts. A detailed thermodynamic analysis was performed for both reactions. The observed reaction behaviour can be predicted by thermodynamics. Product selectivity is catalyst independent, the role of the catalyst is to bring the reactants to approach equilibrium. The partial oxidation is a two-stage process, total oxidation of CH4 is followed by CO2 and H2O reforming of the remaining CH4. A staged addition of O2 to the reactor is tested and recommended. TPSR show that the catalyst surface for CO2 reforming was highly covered with carbonaceous species of four different types; two were identified as reactive intermediates. J.C. Baltzer AG, Science Publishers, 1996 CO2 reforming of CH4 nationallicence partial oxidation of CH4 nationallicence thermodynamic analysis nationallicence reaction intermediates nationallicence TPSR nationallicence Papp H. Institut für Technische Chemie, Universität Leipzig, Linnéstrasse 3, D-04103, Leipzig, Germany aut Schuler P. Institut für Technische Chemie, Universität Leipzig, Linnéstrasse 3, D-04103, Leipzig, Germany aut Zhuang Q. Institut für Technische Chemie, Universität Leipzig, Linnéstrasse 3, D-04103, Leipzig, Germany aut Topics in Catalysis Baltzer Science Publishers, Baarn/Kluwer Academic Publishers 3/3-4(1996-08-01), 299-311 1022-5528 3:3-4<299 1996 3 11244 https://doi.org/10.1007/BF02113856 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02113856 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Papp H. Institut für Technische Chemie, Universität Leipzig, Linnéstrasse 3, D-04103, Leipzig, Germany aut NATIONALLICENCE 700 1- Schuler P. Institut für Technische Chemie, Universität Leipzig, Linnéstrasse 3, D-04103, Leipzig, Germany aut NATIONALLICENCE 700 1- Zhuang Q. Institut für Technische Chemie, Universität Leipzig, Linnéstrasse 3, D-04103, Leipzig, Germany aut NATIONALLICENCE 773 0- Topics in Catalysis Baltzer Science Publishers, Baarn/Kluwer Academic Publishers 3/3-4(1996-08-01), 299-311 1022-5528 3:3-4<299 1996 3 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer