caa a22 4500 477082106 CHVBK 20180405111452.0 cr unu---uuuuu 170330e19960101xx s 000 0 eng 10.1007/BF01922421 doi (NATIONALLICENCE)springer-10.1007/BF01922421 Hydrolysis of isoprenyl diphosphates with the acid phosphatase from Cinnamomum camphora [Elektronische Daten] [S. Izumi, Y. Ashida, T. Yamamitsu, T. Hirata] Direct observations of the enzymatic hydrolysis of C10 acyclic allylic isoprenyl diphosphates by an acid phosphatase from the leaves ofCinnamomum camphora (camphor tree) were made using1H and31P NMR spectrometers. The measurements indicated that the allylic primary diphosphates, geranyl diphosphate and neryl diphosphate, were hydrolyzed to their corresponding alcohols in a sequential manner via their corresponding monophosphates, whereas the allylic tertiary diphosphate, linalyl diphosphate, was hydrolyzed only to its corresponding monophosphate. Birkhäuser Verlag Basel, 1996 Cinnamomum camphora nationallicence 1H NMR nationallicence 31P NMR nationallicence hydrolyses nationallicence acid phosphatase nationallicence geranyl diphosphate nationallicence nerly diphosphate nationallicence linalyl diphosphate nationallicence Izumi S. Department of Chemistry, Faculty of Science, Hiroshima University, 739, Higashi-Hiroshima, (Japan) aut Ashida Y. Department of Chemistry, Faculty of Science, Hiroshima University, 739, Higashi-Hiroshima, (Japan) aut Yamamitsu T. Department of Chemistry, Faculty of Science, Hiroshima University, 739, Higashi-Hiroshima, (Japan) aut Hirata T. Department of Chemistry, Faculty of Science, Hiroshima University, 739, Higashi-Hiroshima, (Japan) aut Experientia Birkhäuser-Verlag 52/1(1996-01-01), 81-84 0014-4754 52:1<81 1996 52 18 https://doi.org/10.1007/BF01922421 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01922421 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Izumi S. Department of Chemistry, Faculty of Science, Hiroshima University, 739, Higashi-Hiroshima, (Japan) aut NATIONALLICENCE 700 1- Ashida Y. Department of Chemistry, Faculty of Science, Hiroshima University, 739, Higashi-Hiroshima, (Japan) aut NATIONALLICENCE 700 1- Yamamitsu T. Department of Chemistry, Faculty of Science, Hiroshima University, 739, Higashi-Hiroshima, (Japan) aut NATIONALLICENCE 700 1- Hirata T. Department of Chemistry, Faculty of Science, Hiroshima University, 739, Higashi-Hiroshima, (Japan) aut NATIONALLICENCE 773 0- Experientia Birkhäuser-Verlag 52/1(1996-01-01), 81-84 0014-4754 52:1<81 1996 52 18 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer