caa a22 4500 477085296 CHVBK 20180405111502.0 cr unu---uuuuu 170330e19960301xx s 000 0 eng 10.1007/BF01166175 doi (NATIONALLICENCE)springer-10.1007/BF01166175 Oxidative addition of 2,2′-dithiosalicylic acid to the cluster [Os3(CO)10)(CH3CN)2] [Elektronische Daten] [Siu-Ming Lee, Wing-Tak Wong] The reaction of 2,2'-dithiosalicylic acid with two equivalents of [Os3(CO)10 (CH3CN)] in THF at −78°C yields yellow crystals of [{Os3(CO)10(μ-H)}2 (O2CC6H4S)2] 1 in moderate yield. Hydrogenetaion of 1 in refluxing CHCl3 affords [Os3(CO)1(μ-H)(O2CC6H5)] 2 in good yield. Structures of 1 and 2 have been established by single crystal X-ray structure analysis. Plenum Publishing Corporation, 1996 Triosmium clusters nationallicence carboxylate linkage nationallicence hydrogenation nationallicence X-ray structure analysis nationallicence Lee Siu-Ming Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong aut Wong Wing-Tak Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/1(1996-03-01), 37-47 1040-7278 7:1<37 1996 7 10876 https://doi.org/10.1007/BF01166175 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01166175 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lee Siu-Ming Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong aut NATIONALLICENCE 700 1- Wong Wing-Tak Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/1(1996-03-01), 37-47 1040-7278 7:1<37 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer