caa a22 4500 477085318 CHVBK 20180405111502.0 cr unu---uuuuu 170330e19960301xx s 000 0 eng 10.1007/BF01166179 doi (NATIONALLICENCE)springer-10.1007/BF01166179 Effects of a vanadate-support on the reactivity of the Bis (Methallyl)Rhodium Complex [{(η3-C4H7)2Rh}2(V4O12)]2−. A comparison with the acetylacetonato complex [Elektronische Daten] [Masaaki Abe, Haruo Akashi, Kiyoshi Isobe, Akihiko Nakanishi, Atsushi Yagasaki] The methallyl moieties of [{(η3-C4H7)2Rh}2(V4O12)]2− couple to yield 2,5-dimethyl-1,5-hexadiene in a selective manner by the action of P(OEt),3, while the reaction of [(η 3-C4H7)2 Rh(acac)] with P(OEt)3 produces a mixture of organic compounds. The result shows that the vanadate support has a significant influence on the reactivity of organometallic complexes. Plenum Publishing Corporation, 1996 Vanadate-supported rhodium complex nationallicence C-C coupling nationallicence rhodium acetylacetonato complex nationallicence Abe Masaaki Institute for Molecular Science, 444, Myodaiji, Okazaki, Japan aut Akashi Haruo Institute for Molecular Science, 444, Myodaiji, Okazaki, Japan aut Isobe Kiyoshi Institute for Molecular Science, 444, Myodaiji, Okazaki, Japan aut Nakanishi Akihiko Department of Chemistry, School of Science, Kwansei Gakuin University, 662, Uegaharaichibancho, Nishinomiya, Japan aut Yagasaki Atsushi Department of Chemistry, School of Science, Kwansei Gakuin University, 662, Uegaharaichibancho, Nishinomiya, Japan aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/1(1996-03-01), 103-107 1040-7278 7:1<103 1996 7 10876 https://doi.org/10.1007/BF01166179 text/html Onlinezugriff via DOI 1 brief-communication jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01166179 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Abe Masaaki Institute for Molecular Science, 444, Myodaiji, Okazaki, Japan aut NATIONALLICENCE 700 1- Akashi Haruo Institute for Molecular Science, 444, Myodaiji, Okazaki, Japan aut NATIONALLICENCE 700 1- Isobe Kiyoshi Institute for Molecular Science, 444, Myodaiji, Okazaki, Japan aut NATIONALLICENCE 700 1- Nakanishi Akihiko Department of Chemistry, School of Science, Kwansei Gakuin University, 662, Uegaharaichibancho, Nishinomiya, Japan aut NATIONALLICENCE 700 1- Yagasaki Atsushi Department of Chemistry, School of Science, Kwansei Gakuin University, 662, Uegaharaichibancho, Nishinomiya, Japan aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/1(1996-03-01), 103-107 1040-7278 7:1<103 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer