caa a22 4500 477085393 CHVBK 20180405111502.0 cr unu---uuuuu 170330e19960901xx s 000 0 eng 10.1007/BF01171189 doi (NATIONALLICENCE)springer-10.1007/BF01171189 The syntheses and crystal structures of two incomplete cubane-like mixed-metal clusters: [{WAg2S3C5H5NS}(PPh3)2(X)] · CH2Cl2 ( X [Elektronische Daten] S, O) [Quanming Wang, Xintao Wu, Qun Huang, Tianlu Sheng] Two incomplete cubane-like clusters [{WAg2S3C5H5NS}(PPh3)2(X)] · CH2Cl2(X = S1, O2) are obtained from the reaction of WS4Ag2(PPh3)3 and WS3Ag2(PPh3)3O with excess C5H5NS, respectively, The crystal structures have been determined by X-ray crystallography. Crystal data for 1, space group P212121,a = 9,053(2),b = 19.543(4),c = 25,262(7) A,Z=4,R(R w )= 0.038(0.046) for 3937 observed reflections with I>5δ(I); for2, space group P212121,a = 18.035(4),b = 24,970(8),c = 9.977(2) A,Z=4,R(R w )= 0.057(0.068) for 2651 observed reflections with I> 3δ(I). Plenum Publishing Corporation, 1996 Incomplete cubane-like cluster nationallicence mixed metal nationallicence tungsten nationallicence Silver nationallicence Pyridine-2-thiol nationallicence Wang Quanming Fujian Institute of Research on the Structure of Matter, and State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut Wu Xintao Fujian Institute of Research on the Structure of Matter, and State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut Huang Qun Fujian Institute of Research on the Structure of Matter, and State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut Sheng Tianlu Fujian Institute of Research on the Structure of Matter, and State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 371-383 1040-7278 7:3<371 1996 7 10876 https://doi.org/10.1007/BF01171189 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01171189 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Quanming Fujian Institute of Research on the Structure of Matter, and State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Wu Xintao Fujian Institute of Research on the Structure of Matter, and State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Huang Qun Fujian Institute of Research on the Structure of Matter, and State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Sheng Tianlu Fujian Institute of Research on the Structure of Matter, and State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 371-383 1040-7278 7:3<371 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer