caa a22 4500 477085407 CHVBK 20180405111502.0 cr unu---uuuuu 170330e19960901xx s 000 0 eng 10.1007/BF01171186 doi (NATIONALLICENCE)springer-10.1007/BF01171186 Cobalt (iron) thiolato complexes containing the Co-ligand phosphine and reaction products of the structural fragment M L 2 L ′ ( L [Elektronische Daten] 1,2-bidentate thiolate, L ′= tertiary phosphine) [Bei-Sheng Kang, Zhong-Ning Chen, Zhong-Yuan Zhou, Han-Qin Liu, Han-Rong Gao, Bo-Mu Wu, Thomas Mak, Yuan-Ba Cai, Yong-Jin Xu, Zhi-Tao Xu] Mono-, di-, tri-, and tetra-nuclear cobalt (iron) complexes containing co-ligands phosphine and thiolate are presented according to the classification by combination of different dentates of the two ligands. Emphasis is being put on the triand tetranuclear cluster complexes of monodentate phosphines and 1,2-bidentate thiolates. These complexes are considered to be constructed based on the general structural fragment (or building block) ML 2L′ (L=1,2-bidentate thiolate,L′=tertiary phosphine). Structural regularities are presented in Tables I, III, IV, and V and discussed. FAB mass spectroscopic data showed the possible fragmentation patterns. Synergism of the cluster skeletons is proposed to explain the occurrence of the distinct structural modes. Plenum Publishing Corporation, 1996 Cobalt (iron) complexes nationallicence thiolate nationallicence phosphine nationallicence structure nationallicence synergism nationallicence Bu n 3P : tri-n-butylphosphine nationallicence dmpe : 1,2-bis(dimethylphosphino)ethane nationallicence dmpm : 1,2-bis(dimethylphosphino)methane nationallicence dppe : 1,2-bis(diphenylphosphino)ethane nationallicence dppep : bis(2-diphenylphosphinoethyl)phenylphosphine nationallicence dppm : 1,1-bis(diphenylphosphino)methane nationallicence dppp : 1,3-bis(diphenylphosphino)propane nationallicence Et3P : triethylphosphine nationallicence Ph3P : triphenylphosphine nationallicence tepme : 1,1,1-tris(diethylphosphinomethyl)ethane nationallicence tppme : 1,1,1-tris(diphenylphosphinomethyl)ethane nationallicence H2bdt : 1,2-benzenedithiol nationallicence H2edt : 1,2-ethanedithiol nationallicence Hmbt : 2-mercaptobenzothiazole nationallicence H2mp : 2-mercaptophenol nationallicence Hmp : 2-hydroxythiophenolate nationallicence Hmpo : 2-mercaptopyridine-N-oxide nationallicence H2mpp : 2-mercapto-3-hydroxypyridine nationallicence Hmpp : 3-hydroxy-2-pyridinothiolate nationallicence H2pdt : 1,2-propanedithiol nationallicence HSPh : thiophenol nationallicence H2tdt : 4-methyl-1,2-benzenedithiol(4-toluenedithiol) nationallicence R2dtc : dialkyldithiocarbamate nationallicence (RO)2dtp : dialkyldithiophosphate nationallicence Kang Bei-Sheng Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China aut Chen Zhong-Ning Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China aut Zhou Zhong-Yuan Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong aut Liu Han-Qin Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China aut Gao Han-Rong Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong aut Wu Bo-Mu Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong aut Mak Thomas Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong aut Cai Yuan-Ba Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut Xu Yong-Jin Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut Xu Zhi-Tao Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 317-340 1040-7278 7:3<317 1996 7 10876 https://doi.org/10.1007/BF01171186 text/html Onlinezugriff via DOI 1 review-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01171186 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kang Bei-Sheng Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China aut NATIONALLICENCE 700 1- Chen Zhong-Ning Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China aut NATIONALLICENCE 700 1- Zhou Zhong-Yuan Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong aut NATIONALLICENCE 700 1- Liu Han-Qin Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China aut NATIONALLICENCE 700 1- Gao Han-Rong Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong aut NATIONALLICENCE 700 1- Wu Bo-Mu Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong aut NATIONALLICENCE 700 1- Mak Thomas Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong aut NATIONALLICENCE 700 1- Cai Yuan-Ba Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Xu Yong-Jin Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Xu Zhi-Tao Department of Chemistry, Zhongshan University, 510275, Guangzhou, Guangdong, China aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 317-340 1040-7278 7:3<317 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer