caa a22 4500 477085415 CHVBK 20180405111502.0 cr unu---uuuuu 170330e19960901xx s 000 0 eng 10.1007/BF01171192 doi (NATIONALLICENCE)springer-10.1007/BF01171192 Synthesis and structure of a dithioether-substituted butene-2-olide-4-ylidene-4 cobalt carbonyl complex [Elektronische Daten] [László Markó, Giuliana Gervasio, Sándor Vastag] The complex (1) has been prepared and its structure determined. Complex1 is the first stable thioether derivative of a metal carbonyl containing only cobalt as metal. It crystallizes in the monoclinic P21/c space group, witha = 13.975( 4 ),b = 11.363( 3 ),c = 14.686(2)A,β = 112.25(2)°,V = 2158.5(7)A3.Z = 4. The solution using direct methods and the anisotropic refinement of all nonhydrogen atoms led toR = 0.039,wR = 0.041 for 3296 reflections with F> 4.0σ(F) Analogous but less stable complexes are formed with 1,6-diphenyl-2,5-dithiahexane and the crown thioether 1,4,7-trithiacyclonane, the latter functioning either as a bidenlate or a tridentate ligand. Plenum Publishing Corporation, 1996 Coball carbonyl nationallicence dithioether nationallicence crown thioether nationallicence bridging carbene nationallicence Markó László Research Group for Petrochemistry of the Hungarian Academy of Sciences, H-8200, Veszprém, Hungary aut Gervasio Giuliana Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Università di Torino, I-10125, Torino, ltaly aut Vastag Sándor Department of Organic Chemistry, University of Veszprém, H-8200, Veszprém, Hungary aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 423-434 1040-7278 7:3<423 1996 7 10876 https://doi.org/10.1007/BF01171192 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01171192 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Markó László Research Group for Petrochemistry of the Hungarian Academy of Sciences, H-8200, Veszprém, Hungary aut NATIONALLICENCE 700 1- Gervasio Giuliana Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Università di Torino, I-10125, Torino, ltaly aut NATIONALLICENCE 700 1- Vastag Sándor Department of Organic Chemistry, University of Veszprém, H-8200, Veszprém, Hungary aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 423-434 1040-7278 7:3<423 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer