caa a22 4500 477085423 CHVBK 20180405111502.0 cr unu---uuuuu 170330e19960901xx s 000 0 eng 10.1007/BF01171185 doi (NATIONALLICENCE)springer-10.1007/BF01171185 DuBois M. Department of Chemistry and Biochemistry, University of Colorado, 80309, Boulder, Colorado aut Reactions of cationic dinuclear molybdenum complexes containing μ-sulfido and μ-thiolate ligands [Elektronische Daten] [M. DuBois] Cationic dinuclear molybdenum complexes with bridging sulfido and thiolate ligands of the formula [(CpMo)2(µ-S2CH2)(µ-S)(µ-SR)]− have been found to show extensive reactivity with molecular hydrogen and with organic molecules that results in the cleavage of C-C, C-N, and C-O bonds. The scope of the reactivity and mechanistic information are reviewed in this paper, and the potential relevance of the reactions to those of heterogeneous molybdenum sulfide catalysts in the hydrotreating process is discussed. Studies of the complex redox chemistry and of the electrophilic and nucelophilic sites within the dinuclear derivatives provide an important basis for understanding the bond cleavage reaction mechanisms, and these topics are also reviewed here. Plenum Publishing Corporation, 1996 Dinuclear nationallicence molybdenum nationallicence sulfido ligands nationallicence thiolates nationallicence hydrogen activation nationallicence hydrogenolysis nationallicence Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 293-315 1040-7278 7:3<293 1996 7 10876 https://doi.org/10.1007/BF01171185 text/html Onlinezugriff via DOI 1 review-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01171185 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- DuBois M. Department of Chemistry and Biochemistry, University of Colorado, 80309, Boulder, Colorado aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 293-315 1040-7278 7:3<293 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer