caa a22 4500 477085431 CHVBK 20180405111502.0 cr unu---uuuuu 170330e19960901xx s 000 0 eng 10.1007/BF01171188 doi (NATIONALLICENCE)springer-10.1007/BF01171188 [Cu12S6(PnPr3)8] and [Cu20S10(PnBu1Bu2)8]: Two sulfur bridged copper clusters with Cu-s cluster cores of known compositions but new structures [Elektronische Daten] [Stefanie Dehnen, Dieter Fenske, Anne Deveson] The synthesis and X-ray determination of two sulfur bridged copper clusters with the known compositions of [Cu12S6(PnPr3)8] and [Cu20S10(PnBu1Bu2)8] but new molecular structures allow a comparison of these isomeric copper sulfide clusters. The Cu-S frameworks of the clusters with twelve copper atoms are highly topologically related and can both be derived flom a hypothetical "naked” [Cu12,S6] cluster that results from theoretical investigations. More dificult is the comparison of the two clusters containing 20 metal atoms. The two cluster types can be called either a "prolate” or an "oblate” isomer of [Cu20S10(pR3)8]. Plenum Publishing Corporation, 1996 Copper sulfide clusters nationallicence X-ray determination nationallicence influence of phosphine ligands nationallicence isomers nationallicence Dehnen Stefanie Institut für Anorganische Chemie der Universität, Engesserstaße, Gebäude-Nr. 30.45, D-76131, Karlsruhe, Germany aut Fenske Dieter Institut für Anorganische Chemie der Universität, Engesserstaße, Gebäude-Nr. 30.45, D-76131, Karlsruhe, Germany aut Deveson Anne Institut für Anorganische Chemie der Universität, Engesserstaße, Gebäude-Nr. 30.45, D-76131, Karlsruhe, Germany aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 351-369 1040-7278 7:3<351 1996 7 10876 https://doi.org/10.1007/BF01171188 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01171188 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Dehnen Stefanie Institut für Anorganische Chemie der Universität, Engesserstaße, Gebäude-Nr. 30.45, D-76131, Karlsruhe, Germany aut NATIONALLICENCE 700 1- Fenske Dieter Institut für Anorganische Chemie der Universität, Engesserstaße, Gebäude-Nr. 30.45, D-76131, Karlsruhe, Germany aut NATIONALLICENCE 700 1- Deveson Anne Institut für Anorganische Chemie der Universität, Engesserstaße, Gebäude-Nr. 30.45, D-76131, Karlsruhe, Germany aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/3(1996-09-01), 351-369 1040-7278 7:3<351 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer