caa a22 4500 477085555 CHVBK 20180405111503.0 cr unu---uuuuu 170330e19961201xx s 000 0 eng 10.1007/BF01165808 doi (NATIONALLICENCE)springer-10.1007/BF01165808 Synthesis, characterization, and reactivity studies of alkylidyne palladium cluster compounds [Elektronische Daten] [Ramon Vilar, D. Michael, P. Mingos] [Pd4(μ3-CR)(μ-Cl)3(PBu 3 1 )4] (R = H, F) have been synthesized from [Pd2(dba)3]. PBu 3 1 and CRCl3 and characterized spectroscopically and in one case by a single crystal X-ray crystallographic analysis, These compounds undergo substitution reactions with LiBr and tertiary phosphines and are catalyst for the polymerization of ethyne. Details of these reactions are discussed for the compound [ Pd4(μ3-CR)(μ-Cl)3(PBu 3 1 )4]. The cluster lbrmation reactions. have been monitored using31P(1H)NMR studies. Plenum Publishing Corporation, 1996 Palladium nationallicence cluster nationallicence alkylidyne nationallicence catalysis nationallicence Vilar Ramon Department of Chemistry, Imperial College of Science, Technology, and Medicine, South Kensington, SW7 2AY, London, UK aut Michael D. Department of Chemistry, Imperial College of Science, Technology, and Medicine, South Kensington, SW7 2AY, London, UK aut Mingos P. Department of Chemistry, Imperial College of Science, Technology, and Medicine, South Kensington, SW7 2AY, London, UK aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/4(1996-12-01), 663-675 1040-7278 7:4<663 1996 7 10876 https://doi.org/10.1007/BF01165808 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01165808 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Vilar Ramon Department of Chemistry, Imperial College of Science, Technology, and Medicine, South Kensington, SW7 2AY, London, UK aut NATIONALLICENCE 700 1- Michael D. Department of Chemistry, Imperial College of Science, Technology, and Medicine, South Kensington, SW7 2AY, London, UK aut NATIONALLICENCE 700 1- Mingos P. Department of Chemistry, Imperial College of Science, Technology, and Medicine, South Kensington, SW7 2AY, London, UK aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/4(1996-12-01), 663-675 1040-7278 7:4<663 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer