caa a22 4500 477085563 CHVBK 20180405111503.0 cr unu---uuuuu 170330e19961201xx s 000 0 eng 10.1007/BF01165801 doi (NATIONALLICENCE)springer-10.1007/BF01165801 A structural variability of copper(I) chloride-tetrahydrothiophene adducts crystallizing in polymeric forms and exhibiting polymorphism: The role of the solvent [Elektronische Daten] [Euro Solari, Stefania De Angelis, Mario Latronico, Carlo Floriani, Angiola Chiesi-Villa, Corrado Rizzoli] The function of the solvent in the self-assembling mode of [CuCl] with tetrahydrothiophene is reported. Copper(l) chloride has been used in the form of [CuCOCl] n , which is slightly soluble in the most common solvents, and to allow an homogeneous phase reaction. The reaction of [CuCOCl] n with THT gave [(CuCl)2(THT)3] x ,1, in CH3OH, [(CuCl)(THT)2] x ,2 in THF [(CuCl)(THT)] x ,3, in CH2Cl2, and [(CuCl)3(THT)2] x ,4, in DME. Compound1 consists of polymeric chains of centrosymmetric Cu2Cl2 dinuclear units bridged by THIT molecules running parallel to the [101] axis. In the structure of2 we found polymeric layers generated from the [(CuCl)(THT)] asymmetric unit by the center of symmetry and by the twofold axis. In compound3 the structure consists of layers generated through the center of symmetry by the [(Cu2Cl2)(THT)2] asymmetric unit, while4 consists of layers generated through the center of symmetry by the [(Cu3Cl3)(THT)2] asymmetric unit. Crystallographic details are as [ollows:2 is monoclinic, space group P21/c.a=9.657(3) A,b=6.441(2) A,c=11.459(3) A,\=111.96(2)°,V=661.0(4) A3. andR=0.075;3 is monoclinic, space group P21/n,a=19.327(7) A,b=6.703(2) A,c=10.116(3) A,ß=103.04(3)°,V=1276.7(7) A3 andR=0.043:4 is triclinic, space group Pl,a=12.513(2) A,b=6.698(1) A,c=9.651(1) A,α=91.98(1)°,\=107.86(1)°,γ=74.59(1)°,V=741.2(2) A3, andR=0.044. Plenum Publishmg Corporation, 1996 Copper(I) polymers nationallicence copper(I) polymorphism nationallicence copper(I) tetrahydrothiophene adducts solvent effects on copper(I) coordination nationallicence Solari Euro Institut de Chimie Minérale et Analytique, BCH, Université de Lausanne, CH-1015, Lausanne, Switzerland aut De Angelis Stefania Institut de Chimie Minérale et Analytique, BCH, Université de Lausanne, CH-1015, Lausanne, Switzerland aut Latronico Mario Institut de Chimie Minérale et Analytique, BCH, Université de Lausanne, CH-1015, Lausanne, Switzerland aut Floriani Carlo Institut de Chimie Minérale et Analytique, BCH, Université de Lausanne, CH-1015, Lausanne, Switzerland aut Chiesi-Villa Angiola Dipartimento di Chimica, Universitá di Parma, I-43100, Parma, Italy aut Rizzoli Corrado Dipartimento di Chimica, Universitá di Parma, I-43100, Parma, Italy aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/4(1996-12-01), 553-566 1040-7278 7:4<553 1996 7 10876 https://doi.org/10.1007/BF01165801 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01165801 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Solari Euro Institut de Chimie Minérale et Analytique, BCH, Université de Lausanne, CH-1015, Lausanne, Switzerland aut NATIONALLICENCE 700 1- De Angelis Stefania Institut de Chimie Minérale et Analytique, BCH, Université de Lausanne, CH-1015, Lausanne, Switzerland aut NATIONALLICENCE 700 1- Latronico Mario Institut de Chimie Minérale et Analytique, BCH, Université de Lausanne, CH-1015, Lausanne, Switzerland aut NATIONALLICENCE 700 1- Floriani Carlo Institut de Chimie Minérale et Analytique, BCH, Université de Lausanne, CH-1015, Lausanne, Switzerland aut NATIONALLICENCE 700 1- Chiesi-Villa Angiola Dipartimento di Chimica, Universitá di Parma, I-43100, Parma, Italy aut NATIONALLICENCE 700 1- Rizzoli Corrado Dipartimento di Chimica, Universitá di Parma, I-43100, Parma, Italy aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/4(1996-12-01), 553-566 1040-7278 7:4<553 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer