caa a22 4500 47708561X CHVBK 20180405111503.0 cr unu---uuuuu 170330e19961201xx s 000 0 eng 10.1007/BF01165809 doi (NATIONALLICENCE)springer-10.1007/BF01165809 Molecular architecture of copper (I) thiometallates: synthesis and characterization of [ReS4Cu3Cl5]3-, a geometry derived from the single cubane-like structure [Elektronische Daten] [Corine Simonnet-Jégat, Sabine Halut, Francis Sécheresse] The new rhenium-copper heteronuclear complex [NEt4]3[ReS4C3Cl5]2, was obtained as black crystals in 65% yield, from the reaction of [NEt4[[ReS4], [NEt4][CuCl2], and [NEt4][Cl] at - 20°C in acetone, while at room temperature without additional chloride [NEt4]2[ReS4Cu3Cl4]1 crystallized as black crystals in 60% yield. Crystal data for2: space group Pl,a=10.331(4) A,b=14.261(2) A,c= I4.458(3) A, α=78.55(1)°, β=81.83(3)°, γ=83.66(3)°,Z=2, 6480 reflections;R=0.058. For1: space group C2/c,a=20.969(5)A,b=12.955(5)A,c=22.827(8)A, β=91.16(2)°, Z=8, 3208 reflections,R = 0.052, The geometry of2 can be viewed as restllting from the opening of the cubane-like structure of1. Plenum Publishing Corporation, 1996 Copper thiometallate nationallicence thiorhenate nationallicence cubane-like structure nationallicence Simonnet-Jégat Corine Laboratoire d'Electrochimie et Chimie de Solides Inorganiques, lecsi, EP CNRS J 0067, Bâtiment Lavoisier, Université de Versailles, 45 avenue des Etats-Unis, 78035, Versailles, France aut Halut Sabine Laboratoire de Chimie des Métaux de transition, URA CNRS 419, Université Pierre et Marie Curie, 4 place Jussieu, 75252, Paris Cedex 05, France aut Sécheresse Francis Laboratoire d'Electrochimie et Chimie de Solides Inorganiques, lecsi, EP CNRS J 0067, Bâtiment Lavoisier, Université de Versailles, 45 avenue des Etats-Unis, 78035, Versailles, France aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/4(1996-12-01), 677-688 1040-7278 7:4<677 1996 7 10876 https://doi.org/10.1007/BF01165809 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01165809 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Simonnet-Jégat Corine Laboratoire d'Electrochimie et Chimie de Solides Inorganiques, lecsi, EP CNRS J 0067, Bâtiment Lavoisier, Université de Versailles, 45 avenue des Etats-Unis, 78035, Versailles, France aut NATIONALLICENCE 700 1- Halut Sabine Laboratoire de Chimie des Métaux de transition, URA CNRS 419, Université Pierre et Marie Curie, 4 place Jussieu, 75252, Paris Cedex 05, France aut NATIONALLICENCE 700 1- Sécheresse Francis Laboratoire d'Electrochimie et Chimie de Solides Inorganiques, lecsi, EP CNRS J 0067, Bâtiment Lavoisier, Université de Versailles, 45 avenue des Etats-Unis, 78035, Versailles, France aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/4(1996-12-01), 677-688 1040-7278 7:4<677 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer