caa a22 4500 477085644 CHVBK 20180405111503.0 cr unu---uuuuu 170330e19960601xx s 000 0 eng 10.1007/BF01166051 doi (NATIONALLICENCE)springer-10.1007/BF01166051 Cleavage of 1,4-diphenylbuta-1,3-diyne on a ruthenium-cobalt cluster: Synthesis and molecular structure of Co2Ru3(μ4−C2Ph)(μ3−C2Ph)(μ-dppm)(μ-CO)2(CO)9 [Elektronische Daten] [Michael Bruce, Natasha Zaitseva, Brian Skelton, Allan White] The reaction between Ru3(μ3-ν2-PhC2C=CPh)(μ-dppm)(CO)8 and Co2(CO)8 afforded dark red Co2Ru3(μ4-C2Ph)(μ3-C2Ph)(μ-dppm)(μ-CO)2(CO)9, shown by an X-ray structure determination to contain a strongly twisted Co2Ru3 bow-tie cluster (central Co), to which two PhC2 units derived from cleavage of the original diyne are attached. One a these is strongly interacting with four metal atoms, the other being attached in the familiar ν1,2ν2-mode. The dppm ligand remains bridging two of the Ru atoms. Plenum Publishing Corporation, 1996 Alkynyl nationallicence bow-tie cluster nationallicence cobalt nationallicence diyne cleavage nationallicence ruthenium nationallicence Bruce Michael Department of Chemistry, University of Adelaide, 5005, Adelaide, South Australia aut Zaitseva Natasha Department of Chemistry, University of Adelaide, 5005, Adelaide, South Australia aut Skelton Brian Department of Chemistry, University of Western Australia, 6907, Nedlands, Western Australia aut White Allan Department of Chemistry, University of Western Australia, 6907, Nedlands, Western Australia aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/2(1996-06-01), 109-119 1040-7278 7:2<109 1996 7 10876 https://doi.org/10.1007/BF01166051 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01166051 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bruce Michael Department of Chemistry, University of Adelaide, 5005, Adelaide, South Australia aut NATIONALLICENCE 700 1- Zaitseva Natasha Department of Chemistry, University of Adelaide, 5005, Adelaide, South Australia aut NATIONALLICENCE 700 1- Skelton Brian Department of Chemistry, University of Western Australia, 6907, Nedlands, Western Australia aut NATIONALLICENCE 700 1- White Allan Department of Chemistry, University of Western Australia, 6907, Nedlands, Western Australia aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/2(1996-06-01), 109-119 1040-7278 7:2<109 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer