caa a22 4500 477085652 CHVBK 20180405111503.0 cr unu---uuuuu 170330e19960601xx s 000 0 eng 10.1007/BF01166055 doi (NATIONALLICENCE)springer-10.1007/BF01166055 [N(PPh3)2]2[{Au3Ag2(C2Ph)6} {Au3Cu2(Cu2Ph)6}]: Co-crystallized pentanuclear bimetallic gold-silver and gold-copper clusters [Elektronische Daten] [M. Sakhawat Hussain, Mazhar Ul-Haque, Omar Abu-Salah] The X-ray structural study of the reaction product of equimolar amounts of [Au3Cu2(C2Ph)6]. [{Au(C2Ph)} n ], and [Ag(C2Ph)} n ] revealed two bimetallic anionic [N(PPh3)2] + [Au3Ag2(C2Ph)6]− and [N(PPh3)2]+[Au3Cu2 (C2 Pg)6] — clusters co-crystallized in one asymmetric unit. Each cluster has trigonal bipyramidal geometry with three gold atoms occupying equatorial planes and two silver or copper atoms in the apical positions. Our earlier conclusion based upon spectroscopic characterization describing the product of be above reaction as trimetallic cluster containing three coinage-metals with an overall composition [Au3CuAg(C2Ph)6]−, was erroneous. Plenum Publishing Corporation, 1996 Gold-silver-copper nationallicence pen tall uclear nationallicence bemtallic nationallicence cluster nationallicence Sakhawat Hussain M. Department of Chemistry, King Fahd University of Petroleum and Minerals, KFUPM Box 1830, 31201, Dhahran, SM Arabia aut Ul-Haque Mazhar Department of Chemistry, King Fahd University of Petroleum and Minerals, KFUPM Box 1830, 31201, Dhahran, SM Arabia aut Abu-Salah Omar Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, 11451, Riyadh, Saudi Arabia aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/2(1996-06-01), 167-177 1040-7278 7:2<167 1996 7 10876 https://doi.org/10.1007/BF01166055 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01166055 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sakhawat Hussain M. Department of Chemistry, King Fahd University of Petroleum and Minerals, KFUPM Box 1830, 31201, Dhahran, SM Arabia aut NATIONALLICENCE 700 1- Ul-Haque Mazhar Department of Chemistry, King Fahd University of Petroleum and Minerals, KFUPM Box 1830, 31201, Dhahran, SM Arabia aut NATIONALLICENCE 700 1- Abu-Salah Omar Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, 11451, Riyadh, Saudi Arabia aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/2(1996-06-01), 167-177 1040-7278 7:2<167 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer