caa a22 4500 477085660 CHVBK 20180405111503.0 cr unu---uuuuu 170330e19960601xx s 000 0 eng 10.1007/BF01166053 doi (NATIONALLICENCE)springer-10.1007/BF01166053 The synthesis of [Fe(CO)3(η1-dppm) {Sn( n -Bu)2}]2 by silicon-tin exchange, its crystal structure and its use as a metallodiphosphine ligand [Elektronische Daten] [Pierre Braunstein, Chantal Charles, Richard Adams, Ralph Layland] The reaction of the siloxyl containing ferrate [Fe(CO)3(η 1-dppm){Si(OMe)3}]−,1 (dppm = Ph2PCH2PPh2) with Sn(OAc)2(n-Bu)2 has yielded the new dimeric complex [Fe(CO)3(η 1-dppm){µ-Sn(n-Bu)2}]2, 3 in 89% yield. Compound3 was characterized crystallographically and was found to be a centrosym-etrical molecule with a rhomboidal Fe2Sn2 cluster at the center. Each iron atom contains meη 1-dppm ligand. Compound3 was found to react with [Pd(dmba) (µ-Cl)]2 (dmba=dimethylbenzylamine) to yield the new complexmer-[Fe(CO)3{Sn(n-Bu)2}(µ-dppm)Pd(dmba)Cl]2, 4 by attachment of a palla-dium grouping to each of the uncoordinated phosphorus atoms in 3. Crystal data for 3: space groupP $$\bar 1$$ ,a=11.399(2) Å, 6=15.98(3) Å, c=10.869(3) Å, α=94.10(2)°.β=100.56(2)°, γ=69.35(1)°,Z=2, 3533 reflections,R=0.034. Plenum Publishing Corporation, 1996 Iran nationallicence siloxyl nationallicence palladium nationallicence tin nationallicence Braunstein Pierre Laboratoire de Chimie de Coordination, URA 0416 CNRS, Université Louis Pasteur, 4 rue Blaise Pascal, F-67070, Strasbourg Cédex, France aut Charles Chantal Laboratoire de Chimie de Coordination, URA 0416 CNRS, Université Louis Pasteur, 4 rue Blaise Pascal, F-67070, Strasbourg Cédex, France aut Adams Richard Department of Chemistry and Biochemistry, University of South Carolina, 29208, Columbia, South Carolina aut Layland Ralph Department of Chemistry and Biochemistry, University of South Carolina, 29208, Columbia, South Carolina aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/2(1996-06-01), 145-154 1040-7278 7:2<145 1996 7 10876 https://doi.org/10.1007/BF01166053 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01166053 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Braunstein Pierre Laboratoire de Chimie de Coordination, URA 0416 CNRS, Université Louis Pasteur, 4 rue Blaise Pascal, F-67070, Strasbourg Cédex, France aut NATIONALLICENCE 700 1- Charles Chantal Laboratoire de Chimie de Coordination, URA 0416 CNRS, Université Louis Pasteur, 4 rue Blaise Pascal, F-67070, Strasbourg Cédex, France aut NATIONALLICENCE 700 1- Adams Richard Department of Chemistry and Biochemistry, University of South Carolina, 29208, Columbia, South Carolina aut NATIONALLICENCE 700 1- Layland Ralph Department of Chemistry and Biochemistry, University of South Carolina, 29208, Columbia, South Carolina aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/2(1996-06-01), 145-154 1040-7278 7:2<145 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer