caa a22 4500 477085709 CHVBK 20180405111503.0 cr unu---uuuuu 170330e19960601xx s 000 0 eng 10.1007/BF01166057 doi (NATIONALLICENCE)springer-10.1007/BF01166057 Synthesis and characterization of the new mixed-metal, mixed-chalcogen clusters Fe2 M (CO)10(μ3-S)(μ3-Te) ( M =W, Mo). crystal structure of Fe2W(CO)10(μ3-S)(μ3-Te) [Elektronische Daten] [Pradeep Mathur, Rajiv Trivedi, P. Sekar, Debojit Chakrabarty, Md. Munkir. Hossain, Vedavati Puranik] The new clusters Fe2 M(CO)10(µ3-S)(µ3-Te), I (M=W) and 2 (M=Mo) have been isolated from the room temperature reaction of Fe2(CO)6(µ-STe) andM(CO)5(THF) (M=W, Mo), respectively. Compounds1 and2 have been characterized by IR, 125 Te NMR spectroscopy, and elemental analysis. The structure of compound1 has been established by X-ray crystallography. It belongs to the triclinic space groupP $$\bar 1$$ witha=6.844(2) Å,b=9.397(2) Å,c=13.681(10) Å, α=81.64(2)°,β=81360r,γ=812(2)°,V=861.2(3) Å3,Z=2,D e =2.835 g cm−3. Full-matrix least-squares refinement of1 converged to R=0.043, andR w .=0.115. The structure consists of a Fe2 WSTe square pyramid and the W atom occupies the apical site of the square pyramid. Plenum Publishing Corporation, 1996 Iron nationallicence tungsten nationallicence molybdenum nationallicence sulfur nationallicence tellurium nationallicence mixed-chalcogen mixed-metal cluster nationallicence Mathur Pradeep Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut Trivedi Rajiv Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut Sekar P. Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut Chakrabarty Debojit Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut Munkir. Hossain Md Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut Puranik Vedavati Physical Chemistry Division, National Chemical Laboratory, 411 008, Pune, India aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/2(1996-06-01), 191-198 1040-7278 7:2<191 1996 7 10876 https://doi.org/10.1007/BF01166057 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01166057 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mathur Pradeep Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut NATIONALLICENCE 700 1- Trivedi Rajiv Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut NATIONALLICENCE 700 1- Sekar P. Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut NATIONALLICENCE 700 1- Chakrabarty Debojit Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut NATIONALLICENCE 700 1- Munkir. Hossain Md Department of Chemistry, Indian Institute of Technology, 400076, Bombay, India aut NATIONALLICENCE 700 1- Puranik Vedavati Physical Chemistry Division, National Chemical Laboratory, 411 008, Pune, India aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 7/2(1996-06-01), 191-198 1040-7278 7:2<191 1996 7 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer