caa a22 4500 47713940X CHVBK 20180405111728.0 cr unu---uuuuu 170330e19970401xx s 000 0 eng 10.1007/BF02767674 doi (NATIONALLICENCE)springer-10.1007/BF02767674 The lead amalgam/lead sulfate electrode redesigned and reassessed [Elektronische Daten] [Patrizia Fusi, Patrizia Mussini] To make the (Pb)Hg‖PbSO4‖SO 4 2− electrode really usable and attractive for extensive application to thermodynamic studies, a new, simplified design and a convenient preparative procedure have been introduced, ensuring stable amalgams and reproducible electrode potentials. The electrode so prepared has been exhaustively characterized both thermodynamically and as a SO 4 2− -sensing electrode, in different sulfate solutions, including H2SO4. The past discrepancies of standard potentials-mainly due to preparation and/or handling problems-are discussed and, for a final resolution of the question, a practical standardization procedure is proposed. Plenum Publishing Corporation, 1997 Lead amalgam nationallicence lead sulphate nationallicence SO 4 2− -reversible electrode nationallicence standard electrode potential nationallicence electrochemical thermodynamics nationallicence Fusi Patrizia Department of Physical Chemistry and Electrochemistry, University of Milan, Via Golgi 19, 20133, Milano, Italy aut Mussini Patrizia Department of Physical Chemistry and Electrochemistry, University of Milan, Via Golgi 19, 20133, Milano, Italy aut Journal of Solution Chemistry Springer US 26/4(1997-04-01), 337-353 0095-9782 26:4<337 1997 26 10953 https://doi.org/10.1007/BF02767674 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02767674 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Fusi Patrizia Department of Physical Chemistry and Electrochemistry, University of Milan, Via Golgi 19, 20133, Milano, Italy aut NATIONALLICENCE 700 1- Mussini Patrizia Department of Physical Chemistry and Electrochemistry, University of Milan, Via Golgi 19, 20133, Milano, Italy aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US 26/4(1997-04-01), 337-353 0095-9782 26:4<337 1997 26 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer