caa a22 4500 47713954X CHVBK 20180405111728.0 cr unu---uuuuu 170330e19970501xx s 000 0 eng 10.1007/BF02767599 doi (NATIONALLICENCE)springer-10.1007/BF02767599 205T1-NMR and UV-Visible spectroscopic determination of the formation constants of aqueous thallium(I) hydroxo-complexes [Elektronische Daten] [P. Sipos, S. Capewell, P. May, G. Hefter, G. Laurenczy, F. Lukacs, R. Roulet] The hydrolysis of T1(I) has been studied at 25°C using205T1-NMR spectroscopy and UV-Vis spectrophotometry in aqueous solutions with ionic strengths maintained by NaC104 at 2, 4, 6, and 8M. The formation constant and the spectral characteristics for the hydroxo complex, T10Hℴ have been determined. At high hydroxide ion concentrations there is clear evidence from the UV-Vis data for the formation of a T1(OH)2-species. The spectrum and an estimated formation constant for this second hydroxo complex are also reported. Plenum Publishing Corporation, 1997 205T1-NMR spectroscopy nationallicence UV-Vis spectrophotometry nationallicence thallium(I) nationallicence hydroxo complexes nationallicence concentrated electrolytes nationallicence hydroxide nationallicence Sipos P. Chemistry, Division of Science, Murdoch University, 6150, Murdoch, WA, Australia aut Capewell S. Chemistry, Division of Science, Murdoch University, 6150, Murdoch, WA, Australia aut May P. Chemistry, Division of Science, Murdoch University, 6150, Murdoch, WA, Australia aut Hefter G. Chemistry, Division of Science, Murdoch University, 6150, Murdoch, WA, Australia aut Laurenczy G. Institut de Chimie Minérale et Analytique, Faculté des Sciences, Université de Lausanne, Lausanne, Switzerland aut Lukacs F. Institut de Chimie Minérale et Analytique, Faculté des Sciences, Université de Lausanne, Lausanne, Switzerland aut Roulet R. Institut de Chimie Minérale et Analytique, Faculté des Sciences, Université de Lausanne, Lausanne, Switzerland aut Journal of Solution Chemistry Springer US 26/5(1997-05-01), 419-431 0095-9782 26:5<419 1997 26 10953 https://doi.org/10.1007/BF02767599 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02767599 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sipos P. Chemistry, Division of Science, Murdoch University, 6150, Murdoch, WA, Australia aut NATIONALLICENCE 700 1- Capewell S. Chemistry, Division of Science, Murdoch University, 6150, Murdoch, WA, Australia aut NATIONALLICENCE 700 1- May P. Chemistry, Division of Science, Murdoch University, 6150, Murdoch, WA, Australia aut NATIONALLICENCE 700 1- Hefter G. Chemistry, Division of Science, Murdoch University, 6150, Murdoch, WA, Australia aut NATIONALLICENCE 700 1- Laurenczy G. Institut de Chimie Minérale et Analytique, Faculté des Sciences, Université de Lausanne, Lausanne, Switzerland aut NATIONALLICENCE 700 1- Lukacs F. Institut de Chimie Minérale et Analytique, Faculté des Sciences, Université de Lausanne, Lausanne, Switzerland aut NATIONALLICENCE 700 1- Roulet R. Institut de Chimie Minérale et Analytique, Faculté des Sciences, Université de Lausanne, Lausanne, Switzerland aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US 26/5(1997-05-01), 419-431 0095-9782 26:5<419 1997 26 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer