caa a22 4500 477139639 CHVBK 20180405111729.0 cr unu---uuuuu 170330e19971101xx s 000 0 eng 10.1007/BF02768826 doi (NATIONALLICENCE)springer-10.1007/BF02768826 Diffusion of Li+ ions in concentrated solutions of LiNO3 in 1,3-diaminopropane [Elektronische Daten] [Hirokazu Hayashi, Yoshio Nakamura] The temperature and composition dependences of the self-diffusion coefficient of Li+ ions were investigated for concentrated solutions of LiNO3 in 1,3-diaminopropane by means of the NMR spin-echo technique from 20 to 50°C. The composition dependence of the activation energy shows a bend around 30 mol % LiNO3. This is consistent with the previous results obtained from the electrical conductivity and the correlation time of the rotational motion of the solvating ions, and suggests that solvent molecules may act as bridges between Li+ ions at higher concentrations of LiNO3. Plenum Publishing Corporation, 1997 Diffusion nationallicence Li+ ions nationallicence concentrated solutions nationallicence LiNO3 nationallicence 1,3-diaminopropane nationallicence NMR nationallicence Hayashi Hirokazu Department of Chemistry, Faculty of Science, Hokkaido University, 060, Sapporo, Japan aut Nakamura Yoshio Department of Chemistry, Faculty of Science, Hokkaido University, 060, Sapporo, Japan aut Journal of Solution Chemistry Springer US 26/11(1997-11-01), 1013-1019 0095-9782 26:11<1013 1997 26 10953 https://doi.org/10.1007/BF02768826 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02768826 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Hayashi Hirokazu Department of Chemistry, Faculty of Science, Hokkaido University, 060, Sapporo, Japan aut NATIONALLICENCE 700 1- Nakamura Yoshio Department of Chemistry, Faculty of Science, Hokkaido University, 060, Sapporo, Japan aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US 26/11(1997-11-01), 1013-1019 0095-9782 26:11<1013 1997 26 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer