naa a22 4500 510734499 CHVBK 20180411083004.0 cr unu---uuuuu 180411e20130701xx s 000 0 eng 10.1007/s12039-013-0438-2 doi (NATIONALLICENCE)springer-10.1007/s12039-013-0438-2 Synthesis and characterization of poly(2-ethylhexyl acrylate) prepared via atom transfer radical polymerization, reverse atom transfer radical polymerization and radical polymerization [Elektronische Daten] [DHRUBA HALOI, BISHNU KOIRY, PRITHWIRAJ MANDAL, NIKHIL SINGHA] This investigation reports a comparative study of poly(2-ethylhexyl acrylate) (PEHA) prepared via atom transfer radical polymerization (ATRP), reverse atom transfer radical polymerization (RATRP) and conventional free radical polymerization (FRP). The molecular weights and the molecular weight distributions of the polymers were measured by gel permeation chromatography (GPC) analysis. Structural characterization of the polymers was carried out by 1H NMR and MALDI-TOF-MS analyses. Thermal properties of the polymers were evaluated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The polymerization results and the thermal properties of PEHAs prepared via ATRP, RATRP and FRP were compared. Graphical Abstract A comparative study of poly(2-ethylhexyl acrylate) (PEHA) prepared via atom transfer radical polymerization (ATRP), reverse atom transfer radical polymerization (RATRP) and conventional free radical polymerization (FRP) is reported. Indian Academy of Sciences, 2013 Atom transfer radical polymerization (ATRP) nationallicence thermal properties nationallicence polymer synthesis nationallicence HALOI DHRUBA Zydex Industries, 25-A Gandhi Oil Mill Compound, Gorwa, 390 016, Vadodara, India aut KOIRY BISHNU Rubber Technology Centre, Indian Institute of Technology Kharagpur, 721 302, Kharagpur, India aut MANDAL PRITHWIRAJ Rubber Technology Centre, Indian Institute of Technology Kharagpur, 721 302, Kharagpur, India aut SINGHA NIKHIL Rubber Technology Centre, Indian Institute of Technology Kharagpur, 721 302, Kharagpur, India aut Journal of Chemical Sciences Springer India 125/4(2013-07-01), 791-797 0974-3626 125:4<791 2013 125 12039 https://doi.org/10.1007/s12039-013-0438-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s12039-013-0438-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- HALOI DHRUBA Zydex Industries, 25-A Gandhi Oil Mill Compound, Gorwa, 390 016, Vadodara, India aut NATIONALLICENCE 700 1- KOIRY BISHNU Rubber Technology Centre, Indian Institute of Technology Kharagpur, 721 302, Kharagpur, India aut NATIONALLICENCE 700 1- MANDAL PRITHWIRAJ Rubber Technology Centre, Indian Institute of Technology Kharagpur, 721 302, Kharagpur, India aut NATIONALLICENCE 700 1- SINGHA NIKHIL Rubber Technology Centre, Indian Institute of Technology Kharagpur, 721 302, Kharagpur, India aut NATIONALLICENCE 773 0- Journal of Chemical Sciences Springer India 125/4(2013-07-01), 791-797 0974-3626 125:4<791 2013 125 12039 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer