naa a22 4500 510752829 CHVBK 20180411083110.0 cr unu---uuuuu 180411e20131101xx s 000 0 eng 10.1007/s11270-013-1759-y doi (NATIONALLICENCE)springer-10.1007/s11270-013-1759-y Interaction of Novel Ionic Liquids with Soils [Elektronische Daten] [Wojciech Mrozik, Christian Jungnickel, Monika Paszkiewicz, Piotr Stepnowski] With the constant development of new ionic liquids, the understanding of the chemical fate of these compounds also needs to be updated. To this effect, the interaction of a number of novel ionic liquids with soils was determined. Therefore, three novel headgroups (ammonium, phosphonium, or pyrrolidinium) with single or quaternary substitution were tested on a variety of soils with high-to-low organic matter content and high-to-low cation exchange capacity, thereby trying to capture the full range of possible soil interactions. It was found that the ionic liquids with single butyl alkyl chain interacted more strongly with the soils (especially with a higher cation exchange capacity), at lower concentrations, than the quad-substituted ionic liquids. However, the quad-substituted ionic liquids interacted more strongly at higher concentrations, due to the double-layer formation, and induced stronger dipole interaction with previously sorbed molecules. The Author(s), 2013 Sorption nationallicence Ionic liquids nationallicence Ammonium nationallicence Phosphonium nationallicence Pyrrolidinium nationallicence Imidazolium nationallicence Natural soils nationallicence Mrozik Wojciech School of Civil Engineering and Geoscience, Newcastle University, NE3 7RU, Newcastle upon Tyne, UK aut Jungnickel Christian Department of Chemical Technology, Faculty of Chemistry, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-233, Gdańsk, Poland aut Paszkiewicz Monika Department of Environmental Analysis, Faculty of Chemistry, University of Gdańsk, ul. Sobieskiego 18/19, 80-952, Gdańsk, Poland aut Stepnowski Piotr Department of Environmental Analysis, Faculty of Chemistry, University of Gdańsk, ul. Sobieskiego 18/19, 80-952, Gdańsk, Poland aut Water, Air, & Soil Pollution Springer Netherlands 224/11(2013-11-01), 1-7 0049-6979 224:11<1 2013 224 11270 https://doi.org/10.1007/s11270-013-1759-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11270-013-1759-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mrozik Wojciech School of Civil Engineering and Geoscience, Newcastle University, NE3 7RU, Newcastle upon Tyne, UK aut NATIONALLICENCE 700 1- Jungnickel Christian Department of Chemical Technology, Faculty of Chemistry, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-233, Gdańsk, Poland aut NATIONALLICENCE 700 1- Paszkiewicz Monika Department of Environmental Analysis, Faculty of Chemistry, University of Gdańsk, ul. Sobieskiego 18/19, 80-952, Gdańsk, Poland aut NATIONALLICENCE 700 1- Stepnowski Piotr Department of Environmental Analysis, Faculty of Chemistry, University of Gdańsk, ul. Sobieskiego 18/19, 80-952, Gdańsk, Poland aut NATIONALLICENCE 773 0- Water, Air, & Soil Pollution Springer Netherlands 224/11(2013-11-01), 1-7 0049-6979 224:11<1 2013 224 11270 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer