naa a22 4500 510803903 CHVBK 20180411083408.0 cr unu---uuuuu 180411e20130401xx s 000 0 eng 10.1007/s11664-012-2395-9 doi (NATIONALLICENCE)springer-10.1007/s11664-012-2395-9 Phase Equilibria in the Sn-Rich Corner of the Ni-Sb-Sn System [Elektronische Daten] [Ratikanta Mishra, Ales Kroupa, Adela Zemanova, Herbert Ipser] Phase equilibria in the ternary Ni-Sb-Sn system are of interest for high-temperature soldering, both considering ternary alloys as solder materials themselves or as the basis for understanding the reactions between Sb-Sn-based solders and Ni-based substrates. Therefore, the Sn-rich corner of the ternary Ni-Sb-Sn phase diagram with Sn content of more than 75at.% was investigated by a combination of powder x-ray diffraction (XRD), differential thermal analysis (DTA), and electron probe microanalysis (EPMA). Ternary phase equilibria and phase compositions of the respective equilibrium phases were determined within the isothermal section at 200°C, and two isopleths were constructed for constant Sn contents of 80at.% and 85at.%. The experiments were supported by CALPHAD-type calculations of this ternary system to yield a consistent reaction scheme which shows four invariant ternary transition reactions in this composition range. A liquidus projection is presented, accompanied by the corresponding Scheil diagram. TMS, 2013 Lead-free solder nationallicence high-temperature solder nationallicence Ni-Sb-Sn system nationallicence phase equilibria nationallicence phase diagram calculation nationallicence Mishra Ratikanta Department of Inorganic Chemistry/Materials Chemistry, University of Vienna, 1090, Wien, Austria aut Kroupa Ales Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 616 62, Brno, Czech Republic aut Zemanova Adela Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 616 62, Brno, Czech Republic aut Ipser Herbert Department of Inorganic Chemistry/Materials Chemistry, University of Vienna, 1090, Wien, Austria aut Journal of Electronic Materials Springer US; http://www.springer-ny.com 42/4(2013-04-01), 646-653 0361-5235 42:4<646 2013 42 11664 https://doi.org/10.1007/s11664-012-2395-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11664-012-2395-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mishra Ratikanta Department of Inorganic Chemistry/Materials Chemistry, University of Vienna, 1090, Wien, Austria aut NATIONALLICENCE 700 1- Kroupa Ales Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 616 62, Brno, Czech Republic aut NATIONALLICENCE 700 1- Zemanova Adela Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 616 62, Brno, Czech Republic aut NATIONALLICENCE 700 1- Ipser Herbert Department of Inorganic Chemistry/Materials Chemistry, University of Vienna, 1090, Wien, Austria aut NATIONALLICENCE 773 0- Journal of Electronic Materials Springer US; http://www.springer-ny.com 42/4(2013-04-01), 646-653 0361-5235 42:4<646 2013 42 11664 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer