naa a22 4500 510815855 CHVBK 20180411083507.0 cr unu---uuuuu 180411e20130301xx s 000 0 eng 10.1007/s11468-012-9427-4 doi (NATIONALLICENCE)springer-10.1007/s11468-012-9427-4 On-Line Optical and Morphological Studies of Silver Nanoparticles Growth Formed by Nanosecond Laser Irradiation of Silver-Exchanged Silicate Glass [Elektronische Daten] [Olivier Véron, Jean-Philippe Blondeau, Michał Grabiec, Aleksandra Wolak, Krzystof Dzierżęga, Nadège Ollier, François Goutaland, Mohamed Sow, Stéphane Pellerin, Nadia Pellerin] Silver-exchanged silicate glass has been irradiated by 532-nm pulsed Nd:YAG laser in order to locally form metallic nanoparticles. The particular interest of this process is to locally control the silver nanoparticles (NPs) growth. Silver ions are exchanged with sodium ions near the glass surface after dumping of a silicate glass few minutes in silver and sodium nitrates molten salt. A low-energy density laser exposure (0.239J/cm2) chosen at the ablation threshold allows to observe the kinetics of the silver NPs growth according to the increasing shots number. An on-line optical measurement is carried out after each shot to identify the most important steps during the irradiation process. According to this measurement, we have determined four steps highlighted by UV/Visible spectrophotometry and we have identified the influence of located surface plasmon resonance. Three combined material analysis methods were used to understand the glass/laser interaction mechanism: we outlined the material volume variations by profilometric method, the element distribution by scanning electron microscopy and finally the structural distribution of the irradiated region by a local infrared investigation. The trend for NPs formation revealed by the UV/Visible spectrophotometry is thus explained by the formation of a ring expelled from a central hole. We highlight that the on-line extinction measurement can be used to data process the NPs evolution. Springer Science+Business Media, LLC, 2012 Silver exchange nationallicence Silicate glass nationallicence Pulsed laser nationallicence UV/Visible nationallicence Infrared nationallicence SEM nationallicence Profilometry nationallicence On-line absorbance nationallicence Coloring nationallicence Ablation nationallicence Material kinetics nationallicence Véron Olivier CEMHTI, UPR 3079, CNRS/Orléans University, Avenue de la Recherche Scientifique, 45071, Orléans Cedex 2, France aut Blondeau Jean-Philippe CEMHTI, UPR 3079, CNRS/Orléans University, Avenue de la Recherche Scientifique, 45071, Orléans Cedex 2, France aut Grabiec Michał Marian Smoluchowski Institute of Physics, Jagiellonian University, ul. Reymonta 4, 30-059, Kraków, Poland aut Wolak Aleksandra Marian Smoluchowski Institute of Physics, Jagiellonian University, ul. Reymonta 4, 30-059, Kraków, Poland aut Dzierżęga Krzystof Marian Smoluchowski Institute of Physics, Jagiellonian University, ul. Reymonta 4, 30-059, Kraków, Poland aut Ollier Nadège Hubert Curien Laboratory, UMR 5516, 18 Rue du Professeur Benoît Lauras, 42000, Saint-Etienne, France aut Goutaland François Hubert Curien Laboratory, UMR 5516, 18 Rue du Professeur Benoît Lauras, 42000, Saint-Etienne, France aut Sow Mohamed Hubert Curien Laboratory, UMR 5516, 18 Rue du Professeur Benoît Lauras, 42000, Saint-Etienne, France aut Pellerin Stéphane GREMI—Site de Bourges, UMR 6606, Orléans University/CNRS, Rue Gaston Berger BP 4043, 18028, Bourges, France aut Pellerin Nadia CEMHTI, UPR 3079, CNRS/Orléans University, Avenue de la Recherche Scientifique, 45071, Orléans Cedex 2, France aut Plasmonics Springer US; http://www.springer-ny.com 8/1(2013-03-01), 93-103 1557-1955 8:1<93 2013 8 11468 https://doi.org/10.1007/s11468-012-9427-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11468-012-9427-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Véron Olivier CEMHTI, UPR 3079, CNRS/Orléans University, Avenue de la Recherche Scientifique, 45071, Orléans Cedex 2, France aut NATIONALLICENCE 700 1- Blondeau Jean-Philippe CEMHTI, UPR 3079, CNRS/Orléans University, Avenue de la Recherche Scientifique, 45071, Orléans Cedex 2, France aut NATIONALLICENCE 700 1- Grabiec Michał Marian Smoluchowski Institute of Physics, Jagiellonian University, ul. Reymonta 4, 30-059, Kraków, Poland aut NATIONALLICENCE 700 1- Wolak Aleksandra Marian Smoluchowski Institute of Physics, Jagiellonian University, ul. Reymonta 4, 30-059, Kraków, Poland aut NATIONALLICENCE 700 1- Dzierżęga Krzystof Marian Smoluchowski Institute of Physics, Jagiellonian University, ul. Reymonta 4, 30-059, Kraków, Poland aut NATIONALLICENCE 700 1- Ollier Nadège Hubert Curien Laboratory, UMR 5516, 18 Rue du Professeur Benoît Lauras, 42000, Saint-Etienne, France aut NATIONALLICENCE 700 1- Goutaland François Hubert Curien Laboratory, UMR 5516, 18 Rue du Professeur Benoît Lauras, 42000, Saint-Etienne, France aut NATIONALLICENCE 700 1- Sow Mohamed Hubert Curien Laboratory, UMR 5516, 18 Rue du Professeur Benoît Lauras, 42000, Saint-Etienne, France aut NATIONALLICENCE 700 1- Pellerin Stéphane GREMI—Site de Bourges, UMR 6606, Orléans University/CNRS, Rue Gaston Berger BP 4043, 18028, Bourges, France aut NATIONALLICENCE 700 1- Pellerin Nadia CEMHTI, UPR 3079, CNRS/Orléans University, Avenue de la Recherche Scientifique, 45071, Orléans Cedex 2, France aut NATIONALLICENCE 773 0- Plasmonics Springer US; http://www.springer-ny.com 8/1(2013-03-01), 93-103 1557-1955 8:1<93 2013 8 11468 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer