naa a22 4500 510819826 CHVBK 20180411083526.0 cr unu---uuuuu 180411e20131201xx s 000 0 eng 10.1007/s11814-013-0182-9 doi (NATIONALLICENCE)springer-10.1007/s11814-013-0182-9 Statistical optimization for oxidation of ethyl benzene over Co-Mn/SBA-15 catalyst by Box-Behnken design [Elektronische Daten] [Vahid Mahdavi, Ali Monajemi] A series of cobalt and manganese catalysts supported on SBA-15 with different loading of Mn+2 and Co+2 were synthesized. These samples were characterized by SEM and XRD techniques. The catalytic activity of these samples was evaluated in the oxidation of ethylbenzene (EB) to produce acetophenone (AP) and benzoic acid (BA) in the liquid phase using tert-butylhydroperoxide (TBHP) as an oxidant. The effects of Co-Mn loading, TBHP: EB molar ratio and temperature on acetophenone and benzoic acid yields were studied by Box-Behnken experimental design to optimize the production of acetophenone and benzoic acid in liquid system. Korean Institute of Chemical Engineers, Seoul, Korea, 2013 Benzoic Acid nationallicence Acetophenone nationallicence SBA-15 nationallicence Cobalt-manganese Catalyst nationallicence Box-Behnken Design nationallicence Mahdavi Vahid Department of Chemistry, Surface Chemistry and Catalysis Division, Faculty of Sciences, Arak University, 38156-8-8349, Arak, Iran aut Monajemi Ali Department of Chemistry, Surface Chemistry and Catalysis Division, Faculty of Sciences, Arak University, 38156-8-8349, Arak, Iran aut Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/12(2013-12-01), 2178-2185 0256-1115 30:12<2178 2013 30 11814 https://doi.org/10.1007/s11814-013-0182-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11814-013-0182-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mahdavi Vahid Department of Chemistry, Surface Chemistry and Catalysis Division, Faculty of Sciences, Arak University, 38156-8-8349, Arak, Iran aut NATIONALLICENCE 700 1- Monajemi Ali Department of Chemistry, Surface Chemistry and Catalysis Division, Faculty of Sciences, Arak University, 38156-8-8349, Arak, Iran aut NATIONALLICENCE 773 0- Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/12(2013-12-01), 2178-2185 0256-1115 30:12<2178 2013 30 11814 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer