naa a22 4500 510820220 CHVBK 20180411083527.0 cr unu---uuuuu 180411e20130301xx s 000 0 eng 10.1007/s11814-012-0204-z doi (NATIONALLICENCE)springer-10.1007/s11814-012-0204-z Glycerol steam reforming over Ni/ γ -Al2O3 catalysts modified by metal oxides [Elektronische Daten] [Zun-Yu Huang, Cheng-Hua Xu, Chuan-Qi Liu, Hui-Wen Xiao, Jun Chen, Yong-Xiang Zhang, Ya-Cong Lei] The metal oxides modified Ni/γ-Al2O3 catalysts for glycerol steam reforming were prepared by impregnation. Characterization results of fresh catalysts indicated that the molybdates modification abated the acidity and the stronger metal-support interaction of Ni/γ-Al2O3 catalysts, leading to a stable catalytic activity. Especially, NiMoLa-CaMg/γ-Al2O3 (NiMoLa/CMA) catalyst exhibited no deactivation along with glycerol complete conversion to stable gaseous products containing 69% H2, 20% CO and 10% CO2 during time-on-stream of 42 h. TPO of spent Ni/γ-Al2O3 catalysts modified by different components showed that the carbon deposit on acidic sites and NiAl2O4 species led to catalysts deactivation. A lower reforming temperature and a higher LHSV and glycerol content were helpful to the production of syngas from GSR over NiMoLa/CMA; the reverse conditions would improve the formation of H2. Korean Institute of Chemical Engineers, Seoul, Korea, 2013 Glycerol nationallicence Steam Reforming nationallicence Syngas nationallicence Hydrogen nationallicence Huang Zun-Yu Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut Xu Cheng-Hua Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut Liu Chuan-Qi Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut Xiao Hui-Wen Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut Chen Jun Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut Zhang Yong-Xiang Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut Lei Ya-Cong Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/3(2013-03-01), 587-592 0256-1115 30:3<587 2013 30 11814 https://doi.org/10.1007/s11814-012-0204-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11814-012-0204-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Huang Zun-Yu Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut NATIONALLICENCE 700 1- Xu Cheng-Hua Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut NATIONALLICENCE 700 1- Liu Chuan-Qi Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut NATIONALLICENCE 700 1- Xiao Hui-Wen Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut NATIONALLICENCE 700 1- Chen Jun Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut NATIONALLICENCE 700 1- Zhang Yong-Xiang Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut NATIONALLICENCE 700 1- Lei Ya-Cong Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, 610225, Chengdu, China aut NATIONALLICENCE 773 0- Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/3(2013-03-01), 587-592 0256-1115 30:3<587 2013 30 11814 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer