naa a22 4500 51082076X CHVBK 20180411083530.0 cr unu---uuuuu 180411e20130401xx s 000 0 eng 10.1007/s11814-012-0205-y doi (NATIONALLICENCE)springer-10.1007/s11814-012-0205-y Effect of support for alcohol-hydrocarbon synthesis from syngas in Cu-based catalyst [Elektronische Daten] [Sun-Hwa Yeon, Dae-Hyun Shin, Nam-Sun Nho, Kyoung-Hee Shin, Chang-Soo Jin, Sung-Chan Nam] Effects of a Cu-based catalyst on the catalytic performance in alcohol-hydrocarbon synthesis from syngas have been investigated, using various supports. Under the different porosities of three supports (zinc oxide, activation carbon, and titanium dioxide), whereas Cu/ZnO produces one liquid phase of major mixed alcohols, Cu/AC and Cu/TiO2 create two phases, alcohol (∼75%) and hydrocarbon (∼25%). X-ray diffraction shows that CuO impregnated on supports undergoes a complete reduction of metallic copper Cu0, which is the real active phase in the catalytic process. The Cu/TiO2 catalyst showed the highest ethanol composition in a mixed alcohol phase under GHSV 18,000 h−1, 30 bar, and 300 °C. Korean Institute of Chemical Engineers, Seoul, Korea, 2013 Ethanol nationallicence Catalyst nationallicence Copper nationallicence Zinc Oxide nationallicence Activated Carbon nationallicence Titanium Dioxide nationallicence Support nationallicence Yeon Sun-Hwa Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut Shin Dae-Hyun Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut Nho Nam-Sun Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut Shin Kyoung-Hee Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut Jin Chang-Soo Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut Nam Sung-Chan Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/4(2013-04-01), 864-870 0256-1115 30:4<864 2013 30 11814 https://doi.org/10.1007/s11814-012-0205-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11814-012-0205-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yeon Sun-Hwa Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut NATIONALLICENCE 700 1- Shin Dae-Hyun Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut NATIONALLICENCE 700 1- Nho Nam-Sun Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut NATIONALLICENCE 700 1- Shin Kyoung-Hee Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut NATIONALLICENCE 700 1- Jin Chang-Soo Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut NATIONALLICENCE 700 1- Nam Sung-Chan Energy Storage Group, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea aut NATIONALLICENCE 773 0- Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/4(2013-04-01), 864-870 0256-1115 30:4<864 2013 30 11814 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer