naa a22 4500 510820956 CHVBK 20180411083531.0 cr unu---uuuuu 180411e20130801xx s 000 0 eng 10.1007/s11814-013-0086-8 doi (NATIONALLICENCE)springer-10.1007/s11814-013-0086-8 Synthesis and characterization of acrylate copolymer containing fluorescein functional group [Elektronische Daten] [Guodong Hui, Weiyun Huang, Yunzhao Song, Deben Chen, Anyong Zhong] We report a novel method to fabricate fluorescent polymer (F-CPA) based on the esterification between acrylate copolymer (CPA) and fluorescein using N, N-dicyclohexylcarbodiimide (DCC)/4-dimethylaminopyridine (DMAP) as catalyst. The resulting copolymer was characterized by Fourier transform-infrared spectroscopy (FT-IR), gel permeation chromatography (GPC), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), ultravioletvisible spectroscopy (UV-Vis) and fluorescence spectroscopy. In addition, the influences of concentration, solvents, pH and metal cations (Cu2+, Fe3+ and Zn2+) on the fluorescent behaviors of F-CPA are discussed in detail. All those observations suggest that the synthesized F-CPA is an excellent luminescent macromolecular material with simple synthesis method and excellent solubility. Moreover, its sensitive fluorescence response behaviors to solvents, pH and metal cations make it to become a polymer-based probe. Korean Institute of Chemical Engineers, Seoul, Korea, 2013 Fluorescein nationallicence Acrylate Copolymer nationallicence DCC/DMAP nationallicence Fluorescent Polymer nationallicence Probe nationallicence Hui Guodong College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut Huang Weiyun College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut Song Yunzhao College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut Chen Deben College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut Zhong Anyong College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/8(2013-08-01), 1609-1613 0256-1115 30:8<1609 2013 30 11814 https://doi.org/10.1007/s11814-013-0086-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11814-013-0086-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Hui Guodong College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut NATIONALLICENCE 700 1- Huang Weiyun College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut NATIONALLICENCE 700 1- Song Yunzhao College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut NATIONALLICENCE 700 1- Chen Deben College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut NATIONALLICENCE 700 1- Zhong Anyong College of Chemistry, Sichuan University, 610064, Chengdu, P. R. China aut NATIONALLICENCE 773 0- Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/8(2013-08-01), 1609-1613 0256-1115 30:8<1609 2013 30 11814 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer