naa a22 4500 510820980 CHVBK 20180411083531.0 cr unu---uuuuu 180411e20130801xx s 000 0 eng 10.1007/s11814-013-0052-5 doi (NATIONALLICENCE)springer-10.1007/s11814-013-0052-5 Catalytic oxidative desulfurization of benzothiophene with hydrogen peroxide over Fe/AC in a biphasic model diesel-acetonitrile system [Elektronische Daten] [Guang-Jian Wang, Jian-Kang Zhang, Ying Liu] Catalytic oxidative desulfurization (Cat-ODS) of benzothiophene (BT) in n-octane has been investigated with hydrogen peroxide (H2O2) over catalysts of activated carbon (AC) supported iron oxide under mild conditions. The catalyst was characterized by N2 adsorption, XRD, SEM/EDS, TPR and XPS. Under the best operating condition for the catalytic oxidative desulfurization—temperature 60 °C, atmospheric pressure, 0.15 g Fe/AC, 18 molar ratio of hydrogen peroxide to sulfur, using acetonitrile as extraction solvent for double extraction—the sulfur content in model diesel fuel (MDF) was reduced from 700 ppmw to 30 ppmw with 95.66% of total sulfur was removed. Korean Institute of Chemical Engineers, Seoul, Korea, 2013 Activated Carbon nationallicence Catalytic Oxidative Desulfurization nationallicence Benzothiophene nationallicence Fe/AC Catalysts nationallicence Sulfur Removal nationallicence Wang Guang-Jian School of Chemical Engineering, Qingdao University of Science and Technology, 266042, Qingdao, Shandong, P. R. China aut Zhang Jian-Kang School of Chemical Engineering, Qingdao University of Science and Technology, 266042, Qingdao, Shandong, P. R. China aut Liu Ying School of Chemical Engineering, Qingdao University of Science and Technology, 266042, Qingdao, Shandong, P. R. China aut Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/8(2013-08-01), 1559-1565 0256-1115 30:8<1559 2013 30 11814 https://doi.org/10.1007/s11814-013-0052-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11814-013-0052-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Guang-Jian School of Chemical Engineering, Qingdao University of Science and Technology, 266042, Qingdao, Shandong, P. R. China aut NATIONALLICENCE 700 1- Zhang Jian-Kang School of Chemical Engineering, Qingdao University of Science and Technology, 266042, Qingdao, Shandong, P. R. China aut NATIONALLICENCE 700 1- Liu Ying School of Chemical Engineering, Qingdao University of Science and Technology, 266042, Qingdao, Shandong, P. R. China aut NATIONALLICENCE 773 0- Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/8(2013-08-01), 1559-1565 0256-1115 30:8<1559 2013 30 11814 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer