naa a22 4500 510821677 CHVBK 20180411083535.0 cr unu---uuuuu 180411e20131101xx s 000 0 eng 10.1007/s11814-013-0147-z doi (NATIONALLICENCE)springer-10.1007/s11814-013-0147-z Preparation and characterization of poly(dimethylsiloxane)-polytetrafluoroethylene (PDMS-PTFE) composite membrane for pervaporation of chloroform from aqueous solution [Elektronische Daten] [De Sun, Bing-Bing Li, Zhen-Liang Xu] Hydrophobic polydimethylsiloxane — polytetrafluoroethylene (PDMS-PTFE) flat-sheet membranes for pervaporation (PV) of chloroform from aqueous solution were successfully fabricated by solution casting method. The structures and the performance of the membranes was characterized by X-ray diffraction (XRD), scanning electron microscope combined with energy dispersive X-ray spectroscopy (SEM-EDXS), Fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA) and the tests of contact angle and mechanical properties. The adding of PTFE particles (<4 μm) in the PDMS matrix enhanced the crystallinity, hydrophobicity, mechanical strength and thermal stability of the membranes. The examinations showed that the PTFE filled PDMS membranes exhibited striking advantages in flux and separation factor as compared with unfilled PDMS membranes. All the filled PDMS membranes with different PTFE content showed excellent PV properties for the separation of chloroform from water. When the content of the PTFE additive in PDMS composite membrane was 30 wt%, membrane performance was the best at feed temperature 50 °C and permeate-side vacuum 0.101MPa. For the 30% PTFE-PDMS membrane, with the increase of the feed temperature from 30 to 60 °C, the total, water and chloroform fluxes as well as the separation factor increased, the apparent activation energy (ΔEa) of total, chloroform and water were 21.08, 66.65 and 11.49 KJ/mol, respectively, with an increase of chloroform concentration in the feed from 50 to 950 ppm, total, water and chloroform fluxes increased but the separation factor decreased. Korean Institute of Chemical Engineers, Seoul, Korea, 2013 Poly(dimethylsiloxane) nationallicence Polytetrafluoroethylene nationallicence Membranes nationallicence Pervaporation nationallicence Sun De State Key Laboratory of Chemical Engineering, Membrane Science and Engineering R&D Lab., Chemical Engineering Research Center, East China University of Science and Technology (ECUST), 130 Meilong Road, 200237, Shanghai, China aut Li Bing-Bing Department of Chemical Engineering, Changchun University of Technology, 2055 Yanan Street, 130012, Changchun, P. R. China aut Xu Zhen-Liang State Key Laboratory of Chemical Engineering, Membrane Science and Engineering R&D Lab., Chemical Engineering Research Center, East China University of Science and Technology (ECUST), 130 Meilong Road, 200237, Shanghai, China aut Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/11(2013-11-01), 2059-2067 0256-1115 30:11<2059 2013 30 11814 https://doi.org/10.1007/s11814-013-0147-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11814-013-0147-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sun De State Key Laboratory of Chemical Engineering, Membrane Science and Engineering R&D Lab., Chemical Engineering Research Center, East China University of Science and Technology (ECUST), 130 Meilong Road, 200237, Shanghai, China aut NATIONALLICENCE 700 1- Li Bing-Bing Department of Chemical Engineering, Changchun University of Technology, 2055 Yanan Street, 130012, Changchun, P. R. China aut NATIONALLICENCE 700 1- Xu Zhen-Liang State Key Laboratory of Chemical Engineering, Membrane Science and Engineering R&D Lab., Chemical Engineering Research Center, East China University of Science and Technology (ECUST), 130 Meilong Road, 200237, Shanghai, China aut NATIONALLICENCE 773 0- Korean Journal of Chemical Engineering Springer US; http://www.springer-ny.com 30/11(2013-11-01), 2059-2067 0256-1115 30:11<2059 2013 30 11814 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer