caa a22 4500 605451184 CHVBK 20210128100150.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1007/s11237-015-9389-7 doi (NATIONALLICENCE)springer-10.1007/s11237-015-9389-7 Exchange Interactions in Cobalt(II) and Nickel(II) Complexes Containing M4(μ3-OH)2 Metal Cores with Distorted Rhombic Topology [Elektronische Daten] [A. Goldberg, G. Aleksandrov, A. Bogomyakov, M. Kiskin, S. Kolotilov, I. Utepova, A. Sidorov, O. Chupakhin, I. Eremenko] Antiferromagnetic interactions between the Co2+ or Ni2+ ions were found in complexes [(μ3 ‐ L)2Co 5 II (μ ‐ OH)2(Piv)7(NO3)] and [(μ3 ‐ L)2(HPiv)Ni 4 II (μ3 ‐ OH)2(Piv)4(NO3)2] (Piv- = pivalic acid anion, L = 1,1′-dipyridazinylferrocene) possessing a metal core with distorted rhombic topology M4(μ3-OH)2. In contrast to the case of symmetrical analogs, the signs of all the exchange interaction parameters J were determined unambiguously. Springer Science+Business Media New York, 2015 pentanuclear complex nationallicence tetranuclear complex nationallicence cobalt(II) nationallicence nickel(II) nationallicence magnetic properties nationallicence ferrocene nationallicence Goldberg A. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut Aleksandrov G. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut Bogomyakov A. Institute "International Tomographic Center”, Siberian Branch, Russian Academy of Sciences, Ul. Institutskaya, 3a, 630090, Novosibirsk, Russian Federation aut Kiskin M. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut Kolotilov S. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, Ukraine aut Utepova I. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ul. S. Kovalevskoy, 22, 620041, Ekaterinburg, Russian Federation aut Sidorov A. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut Chupakhin O. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ul. S. Kovalevskoy, 22, 620041, Ekaterinburg, Russian Federation aut Eremenko I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut Theoretical and Experimental Chemistry Springer US; http://www.springer-ny.com 50/6(2015-01-01), 364-370 0040-5760 50:6<364 2015 50 11237 https://doi.org/10.1007/s11237-015-9389-7 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11237-015-9389-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Goldberg A. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Aleksandrov G. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Bogomyakov A. Institute "International Tomographic Center”, Siberian Branch, Russian Academy of Sciences, Ul. Institutskaya, 3a, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 700 1- Kiskin M. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Kolotilov S. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, Ukraine aut NATIONALLICENCE 700 1- Utepova I. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ul. S. Kovalevskoy, 22, 620041, Ekaterinburg, Russian Federation aut NATIONALLICENCE 700 1- Sidorov A. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Chupakhin O. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ul. S. Kovalevskoy, 22, 620041, Ekaterinburg, Russian Federation aut NATIONALLICENCE 700 1- Eremenko I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, 119991, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Springer US; http://www.springer-ny.com 50/6(2015-01-01), 364-370 0040-5760 50:6<364 2015 50 11237