Activity and Selectivity of an Amphoteric ZrO2-TiO2 Catalyst in the Conversion of Dihydroxyacetone into Ethyl Lactate and Lactic Acid

Verfasser / Beitragende:
[V. Brei, A. Mylin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical and Experimental Chemistry, 50/6(2015-01-01), 384-387
Format:
Artikel (online)
ID: 605451206
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024 7 0 |a 10.1007/s11237-015-9392-z  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s11237-015-9392-z 
245 0 0 |a Activity and Selectivity of an Amphoteric ZrO2-TiO2 Catalyst in the Conversion of Dihydroxyacetone into Ethyl Lactate and Lactic Acid  |h [Elektronische Daten]  |c [V. Brei, A. Mylin] 
520 3 |a A 96% conversion of dihydroxyacetone dissolved in aqueous ethanol mixtures was achieved on an amphoteric ZnO2-TiO2 catalyst in a flow reactor at 140 °C and 1.0 MPa with identical selectivity relative to the two reaction products, lactic acid and ethyl lactate. Variation of the ethanol : water ratio significantly affects the activity and selectivity of the catalyst. The maximum catalyst efficiency was achieved using an aqueous solution containing 65 mass % ethanol. 
540 |a Springer Science+Business Media New York, 2015 
690 7 |a dihydroxyacetone  |2 nationallicence 
690 7 |a ethyl lactate  |2 nationallicence 
690 7 |a lactic acid  |2 nationallicence 
690 7 |a amphoteric catalyst  |2 nationallicence 
700 1 |a Brei  |D V.  |u Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Vul. Generala Naumova, 13, 03164, Kyiv, Ukraine  |4 aut 
700 1 |a Mylin  |D A.  |u Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Vul. Generala Naumova, 13, 03164, Kyiv, Ukraine  |4 aut 
773 0 |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 50/6(2015-01-01), 384-387  |x 0040-5760  |q 50:6<384  |1 2015  |2 50  |o 11237 
856 4 0 |u https://doi.org/10.1007/s11237-015-9392-z  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s11237-015-9392-z  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Brei  |D V.  |u Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Vul. Generala Naumova, 13, 03164, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Mylin  |D A.  |u Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Vul. Generala Naumova, 13, 03164, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 50/6(2015-01-01), 384-387  |x 0040-5760  |q 50:6<384  |1 2015  |2 50  |o 11237