Metal-Centered Photoluminescence of Eu3+ and Tb3+ Coordination Polymers with Dianions of Camphoric and Tetrafluoroterephthalic Acids

Verfasser / Beitragende:
[E. Mikhalyova, S. Smola, K. Garvilenko, V. Dotsenko, I. Eremenko, V. Pavlishchuk]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical and Experimental Chemistry, 51/1(2015-03-01), 30-36
Format:
Artikel (online)
ID: 60545132X
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024 7 0 |a 10.1007/s11237-015-9394-x  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s11237-015-9394-x 
245 0 0 |a Metal-Centered Photoluminescence of Eu3+ and Tb3+ Coordination Polymers with Dianions of Camphoric and Tetrafluoroterephthalic Acids  |h [Elektronische Daten]  |c [E. Mikhalyova, S. Smola, K. Garvilenko, V. Dotsenko, I. Eremenko, V. Pavlishchuk] 
520 3 |a It was shown that coordination polymers [Ln(Camph)(NO3)(MeOH)2]n (1Ln, Ln - Eu, Tb; Camph2--camphorate dianion) and [Ln2(tFbdc)3(DMF)2(H2O)2]n (2Ln, Ln - Eu, Tb; tFbdc2-- tetrafluoroterephtalate dianion) possess metal-centered emission with quantum yields up to 40% under UV-irradiation. It was found that tetrafluoroterephtalate dianion is better antenna ligand than camphorate dianion. It was assumed that for studied complexes the vibrational radiationless deactivation of excited states of ligands influence more significantly on the luminescence characteristics than energy of triplet states of ligands. 
540 |a Springer Science+Business Media New York, 2015 
690 7 |a photoluminescence  |2 nationallicence 
690 7 |a sensibilization  |2 nationallicence 
690 7 |a antenna ligands  |2 nationallicence 
690 7 |a lanthanide coordination polymers  |2 nationallicence 
690 7 |a carboxylate complexes  |2 nationallicence 
700 1 |a Mikhalyova  |D E.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
700 1 |a Smola  |D S.  |u A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfs'ka Doroha, 86, 65080, Odesa, Ukraine  |4 aut 
700 1 |a Garvilenko  |D K.  |u Chembiocenter, Taras Shevchenko National University of Kyiv, Vul. Chervonotkats'ka, 03022, Kyiv, Ukraine  |4 aut 
700 1 |a Dotsenko  |D V.  |u A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfs'ka Doroha, 86, 65080, Odesa, Ukraine  |4 aut 
700 1 |a Eremenko  |D I.  |u N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii Prospekt, 31, 119991, Moscow, Russian Federation  |4 aut 
700 1 |a Pavlishchuk  |D V.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
773 0 |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 51/1(2015-03-01), 30-36  |x 0040-5760  |q 51:1<30  |1 2015  |2 51  |o 11237 
856 4 0 |u https://doi.org/10.1007/s11237-015-9394-x  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
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950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s11237-015-9394-x  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Mikhalyova  |D E.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Smola  |D S.  |u A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfs'ka Doroha, 86, 65080, Odesa, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Garvilenko  |D K.  |u Chembiocenter, Taras Shevchenko National University of Kyiv, Vul. Chervonotkats'ka, 03022, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Dotsenko  |D V.  |u A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfs'ka Doroha, 86, 65080, Odesa, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Eremenko  |D I.  |u N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii Prospekt, 31, 119991, Moscow, Russian Federation  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Pavlishchuk  |D V.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 51/1(2015-03-01), 30-36  |x 0040-5760  |q 51:1<30  |1 2015  |2 51  |o 11237