caa a22 4500 60545132X CHVBK 20210128100151.0 cr unu---uuuuu 210128e20150301xx s 000 0 eng 10.1007/s11237-015-9394-x doi (NATIONALLICENCE)springer-10.1007/s11237-015-9394-x Metal-Centered Photoluminescence of Eu3+ and Tb3+ Coordination Polymers with Dianions of Camphoric and Tetrafluoroterephthalic Acids [Elektronische Daten] [E. Mikhalyova, S. Smola, K. Garvilenko, V. Dotsenko, I. Eremenko, V. Pavlishchuk] It was shown that coordination polymers [Ln(Camph)(NO3)(MeOH)2]n (1Ln, Ln - Eu, Tb; Camph2--camphorate dianion) and [Ln2(tFbdc)3(DMF)2(H2O)2]n (2Ln, Ln - Eu, Tb; tFbdc2-- tetrafluoroterephtalate dianion) possess metal-centered emission with quantum yields up to 40% under UV-irradiation. It was found that tetrafluoroterephtalate dianion is better antenna ligand than camphorate dianion. It was assumed that for studied complexes the vibrational radiationless deactivation of excited states of ligands influence more significantly on the luminescence characteristics than energy of triplet states of ligands. Springer Science+Business Media New York, 2015 photoluminescence nationallicence sensibilization nationallicence antenna ligands nationallicence lanthanide coordination polymers nationallicence carboxylate complexes nationallicence Mikhalyova E. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut Smola S. A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfs'ka Doroha, 86, 65080, Odesa, Ukraine aut Garvilenko K. Chembiocenter, Taras Shevchenko National University of Kyiv, Vul. Chervonotkats'ka, 03022, Kyiv, Ukraine aut Dotsenko V. A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfs'ka Doroha, 86, 65080, Odesa, Ukraine aut Eremenko I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii Prospekt, 31, 119991, Moscow, Russian Federation aut Pavlishchuk V. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut Theoretical and Experimental Chemistry Springer US; http://www.springer-ny.com 51/1(2015-03-01), 30-36 0040-5760 51:1<30 2015 51 11237 https://doi.org/10.1007/s11237-015-9394-x text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11237-015-9394-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mikhalyova E. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut NATIONALLICENCE 700 1- Smola S. A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfs'ka Doroha, 86, 65080, Odesa, Ukraine aut NATIONALLICENCE 700 1- Garvilenko K. Chembiocenter, Taras Shevchenko National University of Kyiv, Vul. Chervonotkats'ka, 03022, Kyiv, Ukraine aut NATIONALLICENCE 700 1- Dotsenko V. A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfs'ka Doroha, 86, 65080, Odesa, Ukraine aut NATIONALLICENCE 700 1- Eremenko I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii Prospekt, 31, 119991, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Pavlishchuk V. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Springer US; http://www.springer-ny.com 51/1(2015-03-01), 30-36 0040-5760 51:1<30 2015 51 11237