Photovoltaic Characteristics of Bis(2-Benzimidazolyl)-Bisthiazole Deposited on TiO2 in the Presence of Zn2+Ions
Gespeichert in:
Verfasser / Beitragende:
[R. Polunin, A. Kozytskiy, S. Kolotilov]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical and Experimental Chemistry, 51/3(2015-07-01), 196-201
Format:
Artikel (online)
Online Zugang:
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| 024 | 7 | 0 | |a 10.1007/s11237-015-9416-8 |2 doi |
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| 245 | 0 | 0 | |a Photovoltaic Characteristics of Bis(2-Benzimidazolyl)-Bisthiazole Deposited on TiO2 in the Presence of Zn2+Ions |h [Elektronische Daten] |c [R. Polunin, A. Kozytskiy, S. Kolotilov] |
| 520 | 3 | |a It was found that bis(2-benzimidazolyl)bisthiazole deposited on nanosized TiO2 in the presence of Zn2+ salts was able to generate a photocurrent upon irradiation by visible light in a cell with a solution of KI in acetonitrile. The activity of this compound was probably caused by the presence of the benzimidazole fragment (electron donor) and the bisthiazole group (electron acceptor), while zinc(II) played a role of agent, required for formation of an insoluble coordination compound on the surface of the TiO2. From comparison of the results with published data it can be concluded that the open-circuit potential of photovoltaic cells containing a benzimidazole fragment decreases with decrease in the energy of lowest unoccupied molecular orbital. | |
| 540 | |a Springer Science+Business Media New York, 2015 | ||
| 690 | 7 | |a bisthiazoles |2 nationallicence | |
| 690 | 7 | |a benzimidazole |2 nationallicence | |
| 690 | 7 | |a zinc(II) |2 nationallicence | |
| 690 | 7 | |a photovoltaic cell |2 nationallicence | |
| 690 | 7 | |a TiO 2 |2 nationallicence | |
| 690 | 7 | |a cyclic voltammetry |2 nationallicence | |
| 700 | 1 | |a Polunin |D R. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | |
| 700 | 1 | |a Kozytskiy |D A. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | |
| 700 | 1 | |a Kolotilov |D S. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | |
| 773 | 0 | |t Theoretical and Experimental Chemistry |d Springer US; http://www.springer-ny.com |g 51/3(2015-07-01), 196-201 |x 0040-5760 |q 51:3<196 |1 2015 |2 51 |o 11237 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s11237-015-9416-8 |q text/html |z Onlinezugriff via DOI |
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| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Polunin |D R. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kozytskiy |D A. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kolotilov |D S. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Theoretical and Experimental Chemistry |d Springer US; http://www.springer-ny.com |g 51/3(2015-07-01), 196-201 |x 0040-5760 |q 51:3<196 |1 2015 |2 51 |o 11237 | ||