Effect of Magnesium Oxide on the Catalytic Properties of ZnO-CuO-MgO/Al2O3/Cordierite in Steam and Steam-Oxygen Reforming of Methanol

Verfasser / Beitragende:
[A. Kapran, S. Orlyk]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical and Experimental Chemistry, 51/4(2015-09-01), 210-215
Format:
Artikel (online)
ID: 605451486
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024 7 0 |a 10.1007/s11237-015-9418-6  |2 doi 
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245 0 0 |a Effect of Magnesium Oxide on the Catalytic Properties of ZnO-CuO-MgO/Al2O3/Cordierite in Steam and Steam-Oxygen Reforming of Methanol  |h [Elektronische Daten]  |c [A. Kapran, S. Orlyk] 
520 3 |a Magnesium oxide in a ZnO-CuO-MgO/Al 2 O 3 /cordierite catalyst contributes to an enhanced yield of hydrogen in steam and steam-oxygen reforming of methanol and to a decreased yield of carbon monoxide in a broad temperature range (230-550 °C). Promotion by magnesium oxide and excess water in the reaction mixture (CH3OH/H2O from 1/5 to 1/10) levels out the sharp decrease in the hydrogen yield at 320-400 °C as a result of a decrease in the reducibility of cupric oxide, which is an active catalyst component. 
540 |a Springer Science+Business Media New York, 2015 
690 7 |a methanol  |2 nationallicence 
690 7 |a steam and steam-oxygen reforming  |2 nationallicence 
690 7 |a hydrogen  |2 nationallicence 
690 7 |a ZnO-MgO-CuO/Al 2 O 3 /cordierite catalysts  |2 nationallicence 
690 7 |a promoting effect of MgO  |2 nationallicence 
700 1 |a Kapran  |D A.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
700 1 |a Orlyk  |D S.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
773 0 |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 51/4(2015-09-01), 210-215  |x 0040-5760  |q 51:4<210  |1 2015  |2 51  |o 11237 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kapran  |D A.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Orlyk  |D S.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 51/4(2015-09-01), 210-215  |x 0040-5760  |q 51:4<210  |1 2015  |2 51  |o 11237