Effect of Magnesium Oxide on the Catalytic Properties of ZnO-CuO-MgO/Al2O3/Cordierite in Steam and Steam-Oxygen Reforming of Methanol
Gespeichert in:
Verfasser / Beitragende:
[A. Kapran, S. Orlyk]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical and Experimental Chemistry, 51/4(2015-09-01), 210-215
Format:
Artikel (online)
Online Zugang:
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| 024 | 7 | 0 | |a 10.1007/s11237-015-9418-6 |2 doi |
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| 245 | 0 | 0 | |a Effect of Magnesium Oxide on the Catalytic Properties of ZnO-CuO-MgO/Al2O3/Cordierite in Steam and Steam-Oxygen Reforming of Methanol |h [Elektronische Daten] |c [A. Kapran, S. Orlyk] |
| 520 | 3 | |a Magnesium oxide in a ZnO-CuO-MgO/Al 2 O 3 /cordierite catalyst contributes to an enhanced yield of hydrogen in steam and steam-oxygen reforming of methanol and to a decreased yield of carbon monoxide in a broad temperature range (230-550 °C). Promotion by magnesium oxide and excess water in the reaction mixture (CH3OH/H2O from 1/5 to 1/10) levels out the sharp decrease in the hydrogen yield at 320-400 °C as a result of a decrease in the reducibility of cupric oxide, which is an active catalyst component. | |
| 540 | |a Springer Science+Business Media New York, 2015 | ||
| 690 | 7 | |a methanol |2 nationallicence | |
| 690 | 7 | |a steam and steam-oxygen reforming |2 nationallicence | |
| 690 | 7 | |a hydrogen |2 nationallicence | |
| 690 | 7 | |a ZnO-MgO-CuO/Al 2 O 3 /cordierite catalysts |2 nationallicence | |
| 690 | 7 | |a promoting effect of MgO |2 nationallicence | |
| 700 | 1 | |a Kapran |D A. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | |
| 700 | 1 | |a Orlyk |D S. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | |
| 773 | 0 | |t Theoretical and Experimental Chemistry |d Springer US; http://www.springer-ny.com |g 51/4(2015-09-01), 210-215 |x 0040-5760 |q 51:4<210 |1 2015 |2 51 |o 11237 | |
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| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kapran |D A. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Orlyk |D S. |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Theoretical and Experimental Chemistry |d Springer US; http://www.springer-ny.com |g 51/4(2015-09-01), 210-215 |x 0040-5760 |q 51:4<210 |1 2015 |2 51 |o 11237 | ||