Kinetics of the Oxidation of Methyl Phenyl Sulfide by Peroxoborate Anions

Verfasser / Beitragende:
[L. Vakhitova, N. Lakhtarenko, A. Popov]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical and Experimental Chemistry, 51/5(2015-11-01), 307-313
Format:
Artikel (online)
ID: 605451559
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024 7 0 |a 10.1007/s11237-015-9430-x  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s11237-015-9430-x 
245 0 0 |a Kinetics of the Oxidation of Methyl Phenyl Sulfide by Peroxoborate Anions  |h [Elektronische Daten]  |c [L. Vakhitova, N. Lakhtarenko, A. Popov] 
520 3 |a A study was carried out on the oxidation of methyl phenyl sulfide by peroxoborate anions (B(OH)3(OOH)- and B(OH)2(OOH) 2 − ) generated from hydrogen peroxide and carbamide peroxysolvate in the presence of boric acid in water and in 2-propanol-water mixtures. The reactivity of the peroxoborate anions is much higher than the reactivity of H2O2. When water is replaced by aqueous alcohol mixtures, the reaction rate decreases. 
540 |a Springer Science+Business Media New York, 2015 
690 7 |a oxidation  |2 nationallicence 
690 7 |a methyl phenyl sulfide  |2 nationallicence 
690 7 |a carbamide peroxysolvate  |2 nationallicence 
690 7 |a hydrogen peroxide  |2 nationallicence 
690 7 |a boric acid  |2 nationallicence 
690 7 |a peroxoborates  |2 nationallicence 
690 7 |a kinetics  |2 nationallicence 
690 7 |a decontaminating systems  |2 nationallicence 
700 1 |a Vakhitova  |D L.  |u L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkivs'ke Shose, 50, 02160, Kyiv, Ukraine  |4 aut 
700 1 |a Lakhtarenko  |D N.  |u L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkivs'ke Shose, 50, 02160, Kyiv, Ukraine  |4 aut 
700 1 |a Popov  |D A.  |u L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkivs'ke Shose, 50, 02160, Kyiv, Ukraine  |4 aut 
773 0 |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 51/5(2015-11-01), 307-313  |x 0040-5760  |q 51:5<307  |1 2015  |2 51  |o 11237 
856 4 0 |u https://doi.org/10.1007/s11237-015-9430-x  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s11237-015-9430-x  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Vakhitova  |D L.  |u L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkivs'ke Shose, 50, 02160, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Lakhtarenko  |D N.  |u L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkivs'ke Shose, 50, 02160, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Popov  |D A.  |u L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkivs'ke Shose, 50, 02160, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 51/5(2015-11-01), 307-313  |x 0040-5760  |q 51:5<307  |1 2015  |2 51  |o 11237