Catalytic Properties of Various Types of Sulfonated Cation-Exchange Resins in the Synthesis of Isopropyl Tert -Butyl Ether

Verfasser / Beitragende:
[T. Serebrii, N. Vlasenko, Yu. Kochkin, P. Strizhak]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical and Experimental Chemistry, 51/2(2015-05-01), 127-132
Format:
Artikel (online)
ID: 60545163X
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024 7 0 |a 10.1007/s11237-015-9407-9  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s11237-015-9407-9 
245 0 0 |a Catalytic Properties of Various Types of Sulfonated Cation-Exchange Resins in the Synthesis of Isopropyl Tert -Butyl Ether  |h [Elektronische Daten]  |c [T. Serebrii, N. Vlasenko, Yu. Kochkin, P. Strizhak] 
520 3 |a The acidic and catalytic characteristics of various types of sulfonated cation-exchange resins, differing in the location of the active phase, in the synthesis of isopropyl tert-butyl ether (IPTBE) were studied. It was established that a sulfonated cation-exchange resin on a wide-pore silica gel support has the highest selectivity with respect to IPTBE (100%). It was shown that mineral-organic sulfonated cation-exchange resins have higher activity than bulk sulfonated cation-exchange resins due to the accessibility of their acid centers for the reagents. 
540 |a Springer Science+Business Media New York, 2015 
690 7 |a isopropyl tert-butyl ether  |2 nationallicence 
690 7 |a sulfonated cation-exchange resins  |2 nationallicence 
690 7 |a acidity  |2 nationallicence 
700 1 |a Serebrii  |D T.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
700 1 |a Vlasenko  |D N.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
700 1 |a Kochkin  |D Yu  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
700 1 |a Strizhak  |D P.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
773 0 |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 51/2(2015-05-01), 127-132  |x 0040-5760  |q 51:2<127  |1 2015  |2 51  |o 11237 
856 4 0 |u https://doi.org/10.1007/s11237-015-9407-9  |q text/html  |z Onlinezugriff via DOI 
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950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s11237-015-9407-9  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Serebrii  |D T.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Vlasenko  |D N.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kochkin  |D Yu  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Strizhak  |D P.  |u L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Theoretical and Experimental Chemistry  |d Springer US; http://www.springer-ny.com  |g 51/2(2015-05-01), 127-132  |x 0040-5760  |q 51:2<127  |1 2015  |2 51  |o 11237