caa a22 4500 60545163X CHVBK 20210128100152.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1007/s11237-015-9407-9 doi (NATIONALLICENCE)springer-10.1007/s11237-015-9407-9 Catalytic Properties of Various Types of Sulfonated Cation-Exchange Resins in the Synthesis of Isopropyl Tert -Butyl Ether [Elektronische Daten] [T. Serebrii, N. Vlasenko, Yu. Kochkin, P. Strizhak] The acidic and catalytic characteristics of various types of sulfonated cation-exchange resins, differing in the location of the active phase, in the synthesis of isopropyl tert-butyl ether (IPTBE) were studied. It was established that a sulfonated cation-exchange resin on a wide-pore silica gel support has the highest selectivity with respect to IPTBE (100%). It was shown that mineral-organic sulfonated cation-exchange resins have higher activity than bulk sulfonated cation-exchange resins due to the accessibility of their acid centers for the reagents. Springer Science+Business Media New York, 2015 isopropyl tert-butyl ether nationallicence sulfonated cation-exchange resins nationallicence acidity nationallicence Serebrii T. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut Vlasenko N. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut Kochkin Yu L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut Strizhak P. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut Theoretical and Experimental Chemistry Springer US; http://www.springer-ny.com 51/2(2015-05-01), 127-132 0040-5760 51:2<127 2015 51 11237 https://doi.org/10.1007/s11237-015-9407-9 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11237-015-9407-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Serebrii T. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut NATIONALLICENCE 700 1- Vlasenko N. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut NATIONALLICENCE 700 1- Kochkin Yu L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut NATIONALLICENCE 700 1- Strizhak P. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Springer US; http://www.springer-ny.com 51/2(2015-05-01), 127-132 0040-5760 51:2<127 2015 51 11237