caa a22 4500 605451648 CHVBK 20210128100152.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1007/s11237-015-9404-z doi (NATIONALLICENCE)springer-10.1007/s11237-015-9404-z Effect of Solvent and Reagent Ratio on the Size of Gold Nanoparticles in Nanocomposites Formed in the Redox Reaction of H[AuCl4] with Two-Dimensional MoS2 [Elektronische Daten] [L. Tsymbal, Ya. Lampeka] It was shown that the redox reaction of tetrachloroauric acid with exfoliated molybdenum disulfide leads to the formation of Au@MoS 2 nanocomposites containing nanoparticles of metallic gold. The reduction rate of the gold(III) is higher in dimethylformamide than in N-methylpyrrolidone. It was shown that the size of the nanoparticles can be controlled by varying the concentration ratio of the reagents C A u I I I / C M o S 2 $$ {C}_{\mathrm{Au}\left(\mathrm{I}\mathrm{I}\mathrm{I}\right)}/\ {C}_{{\mathrm{MoS}}_2} $$ from 2 : 1 to 5 : 1, and under the investigated conditions it increases stepwise from 6.5 to 13 nm. Springer Science+Business Media New York, 2015 nanocomposites nationallicence lamellar materials nationallicence molybdenum(IV) disulfide nationallicence nanoparticles nationallicence metallic gold nationallicence Tsymbal L. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut Lampeka Ya L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut Theoretical and Experimental Chemistry Springer US; http://www.springer-ny.com 51/2(2015-05-01), 109-114 0040-5760 51:2<109 2015 51 11237 https://doi.org/10.1007/s11237-015-9404-z text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11237-015-9404-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Tsymbal L. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut NATIONALLICENCE 700 1- Lampeka Ya L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, 03028, Kyiv, Ukraine aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Springer US; http://www.springer-ny.com 51/2(2015-05-01), 109-114 0040-5760 51:2<109 2015 51 11237