Flow-induced crystallization studied in the RheoDSC device: Quantifying the importance of edge effects

Verfasser / Beitragende:
[Peter Roozemond, Martin van Drongelen, Leander Verbelen, Peter Van Puyvelde, Gerrit Peters]
Ort, Verlag, Jahr:
2015
Enthalten in:
Rheologica Acta, 54/1(2015-01-01), 1-8
Format:
Artikel (online)
ID: 605466300
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024 7 0 |a 10.1007/s00397-014-0820-0  |2 doi 
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245 0 0 |a Flow-induced crystallization studied in the RheoDSC device: Quantifying the importance of edge effects  |h [Elektronische Daten]  |c [Peter Roozemond, Martin van Drongelen, Leander Verbelen, Peter Van Puyvelde, Gerrit Peters] 
520 3 |a Flow-induced crystallization is investigated through short-term shear flow experiments on poly(1-butene) in the RheoDSC device. We demonstrate that the DSC signal shows contributions from spherulitic morphology in the center of the sample and oriented structures at the edge of the sample, the latter being induced by edge effects at the free surface. It is shown that, although small in terms of volume, the crystallization at the edge has a dominating influence on the measured rheology. We show how these kinds of effects can be recognized in stand-alone rheometric studies of flow-induced crystallization. 
540 |a Springer-Verlag Berlin Heidelberg, 2014 
690 7 |a Crystlallization  |2 nationallicence 
690 7 |a Shear-induced structure formation  |2 nationallicence 
690 7 |a Shear flow  |2 nationallicence 
690 7 |a Rotational flow  |2 nationallicence 
690 7 |a Oscillatory shear  |2 nationallicence 
690 7 |a Melt  |2 nationallicence 
700 1 |a Roozemond  |D Peter  |u Department of Mechanical Engineering, Eindhoven University of Technology, P.O. Box 513, 5600MB, Eindhoven, The Netherlands  |4 aut 
700 1 |a van Drongelen  |D Martin  |u Department of Mechanical Engineering, Eindhoven University of Technology, P.O. Box 513, 5600MB, Eindhoven, The Netherlands  |4 aut 
700 1 |a Verbelen  |D Leander  |u Laboratory of Applied Rheology and Polymer Processing, Department of Chemical Engineering, Leuven Material Research Centre, Katholieke Universiteit Leuven, W. de Croylaan 46, B-3001, Leuven, Belgium  |4 aut 
700 1 |a Van Puyvelde  |D Peter  |u Laboratory of Applied Rheology and Polymer Processing, Department of Chemical Engineering, Leuven Material Research Centre, Katholieke Universiteit Leuven, W. de Croylaan 46, B-3001, Leuven, Belgium  |4 aut 
700 1 |a Peters  |D Gerrit  |u Department of Mechanical Engineering, Eindhoven University of Technology, P.O. Box 513, 5600MB, Eindhoven, The Netherlands  |4 aut 
773 0 |t Rheologica Acta  |d Springer Berlin Heidelberg  |g 54/1(2015-01-01), 1-8  |x 0035-4511  |q 54:1<1  |1 2015  |2 54  |o 397 
856 4 0 |u https://doi.org/10.1007/s00397-014-0820-0  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s00397-014-0820-0  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Roozemond  |D Peter  |u Department of Mechanical Engineering, Eindhoven University of Technology, P.O. Box 513, 5600MB, Eindhoven, The Netherlands  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a van Drongelen  |D Martin  |u Department of Mechanical Engineering, Eindhoven University of Technology, P.O. Box 513, 5600MB, Eindhoven, The Netherlands  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Verbelen  |D Leander  |u Laboratory of Applied Rheology and Polymer Processing, Department of Chemical Engineering, Leuven Material Research Centre, Katholieke Universiteit Leuven, W. de Croylaan 46, B-3001, Leuven, Belgium  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Van Puyvelde  |D Peter  |u Laboratory of Applied Rheology and Polymer Processing, Department of Chemical Engineering, Leuven Material Research Centre, Katholieke Universiteit Leuven, W. de Croylaan 46, B-3001, Leuven, Belgium  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Peters  |D Gerrit  |u Department of Mechanical Engineering, Eindhoven University of Technology, P.O. Box 513, 5600MB, Eindhoven, The Netherlands  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Rheologica Acta  |d Springer Berlin Heidelberg  |g 54/1(2015-01-01), 1-8  |x 0035-4511  |q 54:1<1  |1 2015  |2 54  |o 397