Large amplitude oscillatory shear (LAOS) in model colloidal suspensions and glasses: frequency dependence

Verfasser / Beitragende:
[Andreas Poulos, Frédéric Renou, Alan Jacob, Nick Koumakis, George Petekidis]
Ort, Verlag, Jahr:
2015
Enthalten in:
Rheologica Acta, 54/8(2015-08-01), 715-724
Format:
Artikel (online)
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024 7 0 |a 10.1007/s00397-015-0865-8  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s00397-015-0865-8 
245 0 0 |a Large amplitude oscillatory shear (LAOS) in model colloidal suspensions and glasses: frequency dependence  |h [Elektronische Daten]  |c [Andreas Poulos, Frédéric Renou, Alan Jacob, Nick Koumakis, George Petekidis] 
520 3 |a We investigate the effect of frequency on the non-linear large amplitude oscillatory shear (LAOS) response of concentrated colloidal suspensions of model soft and hard spheres at various concentrations, both below and above the glass transition. We show that the anharmonic response in the stress increases with frequency for liquid-like samples but decreases with frequency for solid-like samples. We argue that for samples below the glass transition, higher frequencies involving higher maximum shear rates promote shear thinning and increase anharmonicity. On the other hand, solid-like samples deform plastically at low frequencies as they are subjected to low shear rates within the period. Higher frequencies (higher average shear rates) lead to viscous flow over a larger fraction of the period thereby decreasing anharmonic behavior. We also demonstrate that LAOS experiments in strain-controlled rheometry at moderately high frequencies (ω > 5rad/s) have to be very carefully interpreted, due to the superharmonic instrumental resonance effects. 
540 |a Springer-Verlag Berlin Heidelberg, 2015 
690 7 |a Rheology  |2 nationallicence 
690 7 |a Colloids  |2 nationallicence 
690 7 |a Large amplitude oscillatory shear  |2 nationallicence 
690 7 |a Yielding  |2 nationallicence 
690 7 |a Glass transition  |2 nationallicence 
700 1 |a Poulos  |D Andreas  |u Forschungszentrum Jülich, JCNS-1/ICS-1, 52428, Jülich, Germany  |4 aut 
700 1 |a Renou  |D Frédéric  |u URCOM, EA 3221, FR CNRS 3038, University of Le Havre, 25 rue Philippe Lebon, B.P. 1123, 76063, Le Havre, France  |4 aut 
700 1 |a Jacob  |D Alan  |u IESL-FORTH and Department of Materials Science, University of Crete, Heraklion, Greece  |4 aut 
700 1 |a Koumakis  |D Nick  |u CNR-IPCF Dipartimento di Fisica, Università di Roma "La Sapienza”, Rome, Italy  |4 aut 
700 1 |a Petekidis  |D George  |u IESL-FORTH and Department of Materials Science, University of Crete, Heraklion, Greece  |4 aut 
773 0 |t Rheologica Acta  |d Springer Berlin Heidelberg  |g 54/8(2015-08-01), 715-724  |x 0035-4511  |q 54:8<715  |1 2015  |2 54  |o 397 
856 4 0 |u https://doi.org/10.1007/s00397-015-0865-8  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Poulos  |D Andreas  |u Forschungszentrum Jülich, JCNS-1/ICS-1, 52428, Jülich, Germany  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Renou  |D Frédéric  |u URCOM, EA 3221, FR CNRS 3038, University of Le Havre, 25 rue Philippe Lebon, B.P. 1123, 76063, Le Havre, France  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Jacob  |D Alan  |u IESL-FORTH and Department of Materials Science, University of Crete, Heraklion, Greece  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Koumakis  |D Nick  |u CNR-IPCF Dipartimento di Fisica, Università di Roma "La Sapienza”, Rome, Italy  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Petekidis  |D George  |u IESL-FORTH and Department of Materials Science, University of Crete, Heraklion, Greece  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Rheologica Acta  |d Springer Berlin Heidelberg  |g 54/8(2015-08-01), 715-724  |x 0035-4511  |q 54:8<715  |1 2015  |2 54  |o 397