caa a22 4500 605487154 CHVBK 20210128100449.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1007/s00214-014-1594-2 doi (NATIONALLICENCE)springer-10.1007/s00214-014-1594-2 A new isotherm for multilayer gas adsorption on heterogeneous solid surfaces [Elektronische Daten] [Hadis Bashiri, Samaneh Orouji] In the present study, multilayer gas adsorption on the heterogeneous solid surface has been studied. By considering the heterogeneity of solid surface, a new isotherm for studying multilayer adsorption has been derived. By the use of some assumptions, a new equation for multilayer adsorption on heterogeneous solid surface has been derived. The new isotherm has been analyzed by some of the experimental data of multilayer adsorption at solid/gas interface. A comparison between the new equation and BET isotherm has been provided. The results showed that the new equation has a good conformity with experimental data. It was shown that the new isotherm has more applicability in comparison with BET isotherm. Springer-Verlag Berlin Heidelberg, 2014 Multilayer adsorption nationallicence Solid surface nationallicence Heterogeneity nationallicence BET equation nationallicence Solid/gas interface nationallicence Bashiri Hadis Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran aut Orouji Samaneh Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran aut Theoretical Chemistry Accounts Springer Berlin Heidelberg 134/1(2015-01-01), 1-7 1432-881X 134:1<1 2015 134 214 https://doi.org/10.1007/s00214-014-1594-2 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s00214-014-1594-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bashiri Hadis Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran aut NATIONALLICENCE 700 1- Orouji Samaneh Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran aut NATIONALLICENCE 773 0- Theoretical Chemistry Accounts Springer Berlin Heidelberg 134/1(2015-01-01), 1-7 1432-881X 134:1<1 2015 134 214