Isotope effects on the formation of the lowest rovibrational level of NaH molecule via pump-dump photoassociation

Verfasser / Beitragende:
[Bin-Bin Wang, Yong-Chang Han, Yu-Hui Pang, Shu-Lin Cong, Ying-Yu Niu]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical Chemistry Accounts, 134/7(2015-07-01), 1-10
Format:
Artikel (online)
ID: 605487448
LEADER caa a22 4500
001 605487448
003 CHVBK
005 20210128100450.0
007 cr unu---uuuuu
008 210128e20150701xx s 000 0 eng
024 7 0 |a 10.1007/s00214-015-1680-0  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s00214-015-1680-0 
245 0 0 |a Isotope effects on the formation of the lowest rovibrational level of NaH molecule via pump-dump photoassociation  |h [Elektronische Daten]  |c [Bin-Bin Wang, Yong-Chang Han, Yu-Hui Pang, Shu-Lin Cong, Ying-Yu Niu] 
520 3 |a The isotope effects, substituting H for D in the photoassociation (PA) of the NaH system, on the molecular formation of the lowest rovibrational level, $$|\upsilon =0,\,j=0\rangle$$ | υ = 0 , j = 0 ⟩ , in the electronically ground state $$(\hbox {X}^1\varSigma ^+)$$ ( X 1 Σ + ) via a pump-dump PA process are investigated using the time-dependent wavepacket method. Three cases are taken into account. In the case (1), the rovibrational level $$|\upsilon =10,\,j=1\rangle$$ | υ = 10 , j = 1 ⟩ of the $$\hbox {A}^1\varSigma ^+$$ A 1 Σ + state is taken as the intermediate state for the NaH system. In the case (2), the intermediate state is the same as that of the case (1) except for the NaD system. In the case (3), we set the intermediate state as $$|\upsilon =16,\,j=1\rangle$$ | υ = 16 , j = 1 ⟩ of the $$\hbox {A}^1\varSigma ^+$$ A 1 Σ + state for the NaD system. The PA probabilities of the three cases are $$64\,\%$$ 64 % [case (1)], $$5.5\,\%$$ 5.5 % [case (2)], and $$61\,\%$$ 61 % [case (3)]. It is shown that the PA results of these cases are in accordance with the continuum-bound Franck-Condon factors of the pump process. In addition, the effects of the time-dependent variation of the angular distribution of the prepared excited-state wavepacket on the PA probability are also discussed and compared for the two systems. 
540 |a Springer-Verlag Berlin Heidelberg, 2015 
690 7 |a Quantum wavepacket  |2 nationallicence 
690 7 |a Photoassociation  |2 nationallicence 
690 7 |a Isotope effect  |2 nationallicence 
690 7 |a Pump-dump scheme  |2 nationallicence 
700 1 |a Wang  |D Bin-Bin  |u Department of Physics, Dalian University of Technology, 116024, Dalian, China  |4 aut 
700 1 |a Han  |D Yong-Chang  |u Department of Physics, Dalian University of Technology, 116024, Dalian, China  |4 aut 
700 1 |a Pang  |D Yu-Hui  |u Department of Physics, Dalian University of Technology, 116024, Dalian, China  |4 aut 
700 1 |a Cong  |D Shu-Lin  |u Department of Physics, Dalian University of Technology, 116024, Dalian, China  |4 aut 
700 1 |a Niu  |D Ying-Yu  |u School of Science, Dalian Jiaotong University, 116028, Dalian, China  |4 aut 
773 0 |t Theoretical Chemistry Accounts  |d Springer Berlin Heidelberg  |g 134/7(2015-07-01), 1-10  |x 1432-881X  |q 134:7<1  |1 2015  |2 134  |o 214 
856 4 0 |u https://doi.org/10.1007/s00214-015-1680-0  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s00214-015-1680-0  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Wang  |D Bin-Bin  |u Department of Physics, Dalian University of Technology, 116024, Dalian, China  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Han  |D Yong-Chang  |u Department of Physics, Dalian University of Technology, 116024, Dalian, China  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Pang  |D Yu-Hui  |u Department of Physics, Dalian University of Technology, 116024, Dalian, China  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Cong  |D Shu-Lin  |u Department of Physics, Dalian University of Technology, 116024, Dalian, China  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Niu  |D Ying-Yu  |u School of Science, Dalian Jiaotong University, 116028, Dalian, China  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Theoretical Chemistry Accounts  |d Springer Berlin Heidelberg  |g 134/7(2015-07-01), 1-10  |x 1432-881X  |q 134:7<1  |1 2015  |2 134  |o 214