Isotope effects on the formation of the lowest rovibrational level of NaH molecule via pump-dump photoassociation
Gespeichert in:
Verfasser / Beitragende:
[Bin-Bin Wang, Yong-Chang Han, Yu-Hui Pang, Shu-Lin Cong, Ying-Yu Niu]
Ort, Verlag, Jahr:
2015
Enthalten in:
Theoretical Chemistry Accounts, 134/7(2015-07-01), 1-10
Format:
Artikel (online)
Online Zugang:
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| 024 | 7 | 0 | |a 10.1007/s00214-015-1680-0 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1007/s00214-015-1680-0 | ||
| 245 | 0 | 0 | |a Isotope effects on the formation of the lowest rovibrational level of NaH molecule via pump-dump photoassociation |h [Elektronische Daten] |c [Bin-Bin Wang, Yong-Chang Han, Yu-Hui Pang, Shu-Lin Cong, Ying-Yu Niu] |
| 520 | 3 | |a The isotope effects, substituting H for D in the photoassociation (PA) of the NaH system, on the molecular formation of the lowest rovibrational level, $$|\upsilon =0,\,j=0\rangle$$ | υ = 0 , j = 0 ⟩ , in the electronically ground state $$(\hbox {X}^1\varSigma ^+)$$ ( X 1 Σ + ) via a pump-dump PA process are investigated using the time-dependent wavepacket method. Three cases are taken into account. In the case (1), the rovibrational level $$|\upsilon =10,\,j=1\rangle$$ | υ = 10 , j = 1 ⟩ of the $$\hbox {A}^1\varSigma ^+$$ A 1 Σ + state is taken as the intermediate state for the NaH system. In the case (2), the intermediate state is the same as that of the case (1) except for the NaD system. In the case (3), we set the intermediate state as $$|\upsilon =16,\,j=1\rangle$$ | υ = 16 , j = 1 ⟩ of the $$\hbox {A}^1\varSigma ^+$$ A 1 Σ + state for the NaD system. The PA probabilities of the three cases are $$64\,\%$$ 64 % [case (1)], $$5.5\,\%$$ 5.5 % [case (2)], and $$61\,\%$$ 61 % [case (3)]. It is shown that the PA results of these cases are in accordance with the continuum-bound Franck-Condon factors of the pump process. In addition, the effects of the time-dependent variation of the angular distribution of the prepared excited-state wavepacket on the PA probability are also discussed and compared for the two systems. | |
| 540 | |a Springer-Verlag Berlin Heidelberg, 2015 | ||
| 690 | 7 | |a Quantum wavepacket |2 nationallicence | |
| 690 | 7 | |a Photoassociation |2 nationallicence | |
| 690 | 7 | |a Isotope effect |2 nationallicence | |
| 690 | 7 | |a Pump-dump scheme |2 nationallicence | |
| 700 | 1 | |a Wang |D Bin-Bin |u Department of Physics, Dalian University of Technology, 116024, Dalian, China |4 aut | |
| 700 | 1 | |a Han |D Yong-Chang |u Department of Physics, Dalian University of Technology, 116024, Dalian, China |4 aut | |
| 700 | 1 | |a Pang |D Yu-Hui |u Department of Physics, Dalian University of Technology, 116024, Dalian, China |4 aut | |
| 700 | 1 | |a Cong |D Shu-Lin |u Department of Physics, Dalian University of Technology, 116024, Dalian, China |4 aut | |
| 700 | 1 | |a Niu |D Ying-Yu |u School of Science, Dalian Jiaotong University, 116028, Dalian, China |4 aut | |
| 773 | 0 | |t Theoretical Chemistry Accounts |d Springer Berlin Heidelberg |g 134/7(2015-07-01), 1-10 |x 1432-881X |q 134:7<1 |1 2015 |2 134 |o 214 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s00214-015-1680-0 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1007/s00214-015-1680-0 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Wang |D Bin-Bin |u Department of Physics, Dalian University of Technology, 116024, Dalian, China |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Han |D Yong-Chang |u Department of Physics, Dalian University of Technology, 116024, Dalian, China |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Pang |D Yu-Hui |u Department of Physics, Dalian University of Technology, 116024, Dalian, China |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Cong |D Shu-Lin |u Department of Physics, Dalian University of Technology, 116024, Dalian, China |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Niu |D Ying-Yu |u School of Science, Dalian Jiaotong University, 116028, Dalian, China |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Theoretical Chemistry Accounts |d Springer Berlin Heidelberg |g 134/7(2015-07-01), 1-10 |x 1432-881X |q 134:7<1 |1 2015 |2 134 |o 214 | ||