Helical molecular redox actuators with pancake bonds?
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| 024 | 7 | 0 | |a 10.1007/s00214-015-1750-3 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1007/s00214-015-1750-3 | ||
| 245 | 0 | 0 | |a Helical molecular redox actuators with pancake bonds? |h [Elektronische Daten] |c [Pierre Beaujean, Miklos Kertesz] |
| 520 | 3 | |a In an attempt to design molecular electromechanical actuators with large deformation response, we present here three helicene-like compounds, which offer significant strain above 5% due to two-electron charge transfer (CT). The shrinking induced by CT is a quantum mechanical orbital effect. A good π-π overlap across the helical pitch is critical for this type of actuation. The relevant overlap refers to frontier orbitals that are involved in the CT, and it has some features common with π-π stacking pancake bonds; however, these molecules do not represent all aspects of typical pancake bonding. This overlap is accompanied by a change in the bond length alternation pattern indicating significant change in π-conjugation. Additionally, two further helicene-like molecules included in this study also indicate large electromechanical actuation, but a simple orbital interpretation is not available in those cases. | |
| 540 | |a Springer-Verlag Berlin Heidelberg, 2015 | ||
| 690 | 7 | |a Molecular actuators |2 nationallicence | |
| 690 | 7 | |a Charge transfer |2 nationallicence | |
| 690 | 7 | |a Helical structure |2 nationallicence | |
| 690 | 7 | |a π-π Overlap |2 nationallicence | |
| 690 | 7 | |a Density functional theory computations |2 nationallicence | |
| 700 | 1 | |a Beaujean |D Pierre |u Laboratoire de Chimie Théorique, Unité de Chimie Physique Théorique et Structurale, Université de Namur, rue de Bruxelles 61, 5000, Namur, Belgium |4 aut | |
| 700 | 1 | |a Kertesz |D Miklos |u Department of Chemistry and Institute of Soft Matter, Georgetown University, 37th and O Streets, NW, 20057-1227, Washington, DC, USA |4 aut | |
| 773 | 0 | |t Theoretical Chemistry Accounts |d Springer Berlin Heidelberg |g 134/12(2015-12-01), 1-10 |x 1432-881X |q 134:12<1 |1 2015 |2 134 |o 214 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s00214-015-1750-3 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1007/s00214-015-1750-3 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Beaujean |D Pierre |u Laboratoire de Chimie Théorique, Unité de Chimie Physique Théorique et Structurale, Université de Namur, rue de Bruxelles 61, 5000, Namur, Belgium |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kertesz |D Miklos |u Department of Chemistry and Institute of Soft Matter, Georgetown University, 37th and O Streets, NW, 20057-1227, Washington, DC, USA |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Theoretical Chemistry Accounts |d Springer Berlin Heidelberg |g 134/12(2015-12-01), 1-10 |x 1432-881X |q 134:12<1 |1 2015 |2 134 |o 214 | ||