Interaction between cationic monomer and sodium dodecyl sulfate in concentrated aqueous solutions: EPR spectroscopy and rotational viscometry

Verfasser / Beitragende:
[Yu. Shulevich, M. Motyakin, Yu. Zakharova, E. Dukhanina, A. Wasserman, A. Navrotskii, I. Novakov]
Ort, Verlag, Jahr:
2015
Enthalten in:
Colloid Journal, 77/1(2015-01-01), 108-114
Format:
Artikel (online)
ID: 605489106
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024 7 0 |a 10.1134/S1061933X15010160  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1061933X15010160 
245 0 0 |a Interaction between cationic monomer and sodium dodecyl sulfate in concentrated aqueous solutions: EPR spectroscopy and rotational viscometry  |h [Elektronische Daten]  |c [Yu. Shulevich, M. Motyakin, Yu. Zakharova, E. Dukhanina, A. Wasserman, A. Navrotskii, I. Novakov] 
520 3 |a The interaction of a cationic monomer, trimethyl[methacryloxyethyl]ammonium methyl sulfate, with sodium dodecyl sulfate (SDS) has been studied in relatively concentrated solutions containing SDS (70-500 mM) and the monomer (from 7 mM to 2.5 M). The high concentrations of the components do not prevent the monomer from bonding to oppositely charged SDSs, which confirms the possibility in principle to polymerize ionic monomers through a template mechanism using micelles of oppositely charged surfactants as templates. The range of component ratios 0.5 ≤ [monomer]/[SDS] ≤ 2 is most promising for realization of the template mechanism of polymerization. The effect of SDS on the macroscopic and microscopic properties of the system significantly and to a maximum extent decreases upon a further rise in the relative concentration of the monomer. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Shulevich  |D Yu  |u Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia  |4 aut 
700 1 |a Motyakin  |D M.  |u Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119991, Moscow, Russia  |4 aut 
700 1 |a Zakharova  |D Yu  |u Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia  |4 aut 
700 1 |a Dukhanina  |D E.  |u Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia  |4 aut 
700 1 |a Wasserman  |D A.  |u Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119991, Moscow, Russia  |4 aut 
700 1 |a Navrotskii  |D A.  |u Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia  |4 aut 
700 1 |a Novakov  |D I.  |u Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia  |4 aut 
773 0 |t Colloid Journal  |d Pleiades Publishing  |g 77/1(2015-01-01), 108-114  |x 1061-933X  |q 77:1<108  |1 2015  |2 77  |o 10595 
856 4 0 |u https://doi.org/10.1134/S1061933X15010160  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1061933X15010160  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Shulevich  |D Yu  |u Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Motyakin  |D M.  |u Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Zakharova  |D Yu  |u Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Dukhanina  |D E.  |u Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Wasserman  |D A.  |u Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Navrotskii  |D A.  |u Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Novakov  |D I.  |u Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Colloid Journal  |d Pleiades Publishing  |g 77/1(2015-01-01), 108-114  |x 1061-933X  |q 77:1<108  |1 2015  |2 77  |o 10595