caa a22 4500 605489106 CHVBK 20210128100458.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1134/S1061933X15010160 doi (NATIONALLICENCE)springer-10.1134/S1061933X15010160 Interaction between cationic monomer and sodium dodecyl sulfate in concentrated aqueous solutions: EPR spectroscopy and rotational viscometry [Elektronische Daten] [Yu. Shulevich, M. Motyakin, Yu. Zakharova, E. Dukhanina, A. Wasserman, A. Navrotskii, I. Novakov] The interaction of a cationic monomer, trimethyl[methacryloxyethyl]ammonium methyl sulfate, with sodium dodecyl sulfate (SDS) has been studied in relatively concentrated solutions containing SDS (70-500 mM) and the monomer (from 7 mM to 2.5 M). The high concentrations of the components do not prevent the monomer from bonding to oppositely charged SDSs, which confirms the possibility in principle to polymerize ionic monomers through a template mechanism using micelles of oppositely charged surfactants as templates. The range of component ratios 0.5 ≤ [monomer]/[SDS] ≤ 2 is most promising for realization of the template mechanism of polymerization. The effect of SDS on the macroscopic and microscopic properties of the system significantly and to a maximum extent decreases upon a further rise in the relative concentration of the monomer. Pleiades Publishing, Ltd., 2015 Shulevich Yu Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia aut Motyakin M. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119991, Moscow, Russia aut Zakharova Yu Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia aut Dukhanina E. Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia aut Wasserman A. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119991, Moscow, Russia aut Navrotskii A. Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia aut Novakov I. Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia aut Colloid Journal Pleiades Publishing 77/1(2015-01-01), 108-114 1061-933X 77:1<108 2015 77 10595 https://doi.org/10.1134/S1061933X15010160 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S1061933X15010160 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Shulevich Yu Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia aut NATIONALLICENCE 700 1- Motyakin M. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Zakharova Yu Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia aut NATIONALLICENCE 700 1- Dukhanina E. Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia aut NATIONALLICENCE 700 1- Wasserman A. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Navrotskii A. Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia aut NATIONALLICENCE 700 1- Novakov I. Volgograd State Technical University, pr. Lenina 28, 400005, Volgograd, Russia aut NATIONALLICENCE 773 0- Colloid Journal Pleiades Publishing 77/1(2015-01-01), 108-114 1061-933X 77:1<108 2015 77 10595