Equilibrium studies on the removal of cadmium ion on amberlite IR-120 sorbent

Verfasser / Beitragende:
[M. Khalil, Y. El-Aryan, E. Abdel-Galil]
Ort, Verlag, Jahr:
2015
Enthalten in:
Colloid Journal, 77/6(2015-11-01), 745-753
Format:
Artikel (online)
ID: 605489335
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024 7 0 |a 10.1134/S1061933X15060113  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1061933X15060113 
245 0 0 |a Equilibrium studies on the removal of cadmium ion on amberlite IR-120 sorbent  |h [Elektronische Daten]  |c [M. Khalil, Y. El-Aryan, E. Abdel-Galil] 
520 3 |a Adsorption kinetics and isotherms for Cd(II) ions on Amberlite IR-120 in a batch process have been studied under different conditions. The influence of various experimental parameters such as the pH, amount of adsorbent material, initial Cd(II) concentration, contact time and solution temperature, on the removal of cadmium ions has been investigated. The experimental isotherms were analyzed using the Langmuir and Freundlich models. The results suggest that the adsorption of Cd(II) ions on Amberlite IR-120 follows the Langmuir model. The adsorption capacities amounted for 250.63, 258.39 and 259.74 mg/g adsorbent at 28, 50 and 70°C, respectively. Two kinetic models were applied to fit the experimental kinetic data. The best fit was obtained with pseudo-second order model. The thermodynamic parameters were also determined. The activation energy calculated from the rate coefficients at different temperatures was 37.45 kJ/mol. The value of the heat of adsorption suggests the endothermic nature of the cation exchange process. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Khalil  |D M.  |u Hot Laboratory Center, Atomic Energy Authority, P. No. 13759, Cairo, Egypt  |4 aut 
700 1 |a El-Aryan  |D Y.  |u Hot Laboratory Center, Atomic Energy Authority, P. No. 13759, Cairo, Egypt  |4 aut 
700 1 |a Abdel-Galil  |D E.  |u Hot Laboratory Center, Atomic Energy Authority, P. No. 13759, Cairo, Egypt  |4 aut 
773 0 |t Colloid Journal  |d Pleiades Publishing  |g 77/6(2015-11-01), 745-753  |x 1061-933X  |q 77:6<745  |1 2015  |2 77  |o 10595 
856 4 0 |u https://doi.org/10.1134/S1061933X15060113  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1061933X15060113  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Khalil  |D M.  |u Hot Laboratory Center, Atomic Energy Authority, P. No. 13759, Cairo, Egypt  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a El-Aryan  |D Y.  |u Hot Laboratory Center, Atomic Energy Authority, P. No. 13759, Cairo, Egypt  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Abdel-Galil  |D E.  |u Hot Laboratory Center, Atomic Energy Authority, P. No. 13759, Cairo, Egypt  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Colloid Journal  |d Pleiades Publishing  |g 77/6(2015-11-01), 745-753  |x 1061-933X  |q 77:6<745  |1 2015  |2 77  |o 10595