Interaction of diphenylpolyenes with SiO2 surface under conditions of liquid chromatography

Verfasser / Beitragende:
[K. Polunin, I. Polunina, V. Roldughin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Colloid Journal, 77/3(2015-05-01), 327-332
Format:
Artikel (online)
ID: 605489548
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024 7 0 |a 10.1134/S1061933X15020131  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1061933X15020131 
245 0 0 |a Interaction of diphenylpolyenes with SiO2 surface under conditions of liquid chromatography  |h [Elektronische Daten]  |c [K. Polunin, I. Polunina, V. Roldughin] 
520 3 |a Thin-layer and high-performance liquid chromatography methods have been employed to study the interaction of diphenylpolyenes with the surfaces of SiO2 (silica gel) and SiO2-C18 in organic and aqueous media. Electronic absorption spectra of diphenylpolyenes have been measured in different solvents, and the constants of their chromatographic retention on the solid phase surface have been determined. The interaction of diphenylpolyenes with SiO2 surface in a binary organic solvent and with SiO2-C18 surface in a water-organic solvent has been shown to intensify in the series cis-1,2-diphenylethylene < trans-1,2-diphenylethylene < trans-1,4-diphenyl-1,3-butadiene < trans-1,6-diphenyl-1,3,5-hexatriene. The retention constants of diphenylpolyenes have been revealed to depend on the geometry and configuration of their molecules, the length of an olefin fragment, and the nature and polarity of an eluent. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Polunin  |D K.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia  |4 aut 
700 1 |a Polunina  |D I.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia  |4 aut 
700 1 |a Roldughin  |D V.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia  |4 aut 
773 0 |t Colloid Journal  |d Pleiades Publishing  |g 77/3(2015-05-01), 327-332  |x 1061-933X  |q 77:3<327  |1 2015  |2 77  |o 10595 
856 4 0 |u https://doi.org/10.1134/S1061933X15020131  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1061933X15020131  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Polunin  |D K.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Polunina  |D I.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Roldughin  |D V.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Colloid Journal  |d Pleiades Publishing  |g 77/3(2015-05-01), 327-332  |x 1061-933X  |q 77:3<327  |1 2015  |2 77  |o 10595