Synthesis and characterization of novel cross-linking poly(butyl acrylate- co -isobornyl methacrylate) colloids prepared via semi-continuous seeded emulsion polymerization

Verfasser / Beitragende:
[Lijun Chen, Zhongbin Bao, Zhengrong Fu, Wen Li]
Ort, Verlag, Jahr:
2015
Enthalten in:
Colloid Journal, 77/3(2015-05-01), 374-381
Format:
Artikel (online)
ID: 605489580
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024 7 0 |a 10.1134/S1061933X15030059  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1061933X15030059 
245 0 0 |a Synthesis and characterization of novel cross-linking poly(butyl acrylate- co -isobornyl methacrylate) colloids prepared via semi-continuous seeded emulsion polymerization  |h [Elektronische Daten]  |c [Lijun Chen, Zhongbin Bao, Zhengrong Fu, Wen Li] 
520 3 |a The novel cross-linking (butyl acrylate-co-isobornyl methacrylate) colloids are prepared via semi-continuous seeded emulsion polymerization of butyl acrylate, isobornyl methacrylate and N-methylol acrylamide in aqueous phase using mixture of polyethylene glycol mono(octylphenyl) ether and sodium dodecyl sulphate as emulsifier and potassium persulphate as initiator. The optimal composition for preparing the novel cross-linking colloid was determined, and the structure of the as-prepared colloid was confirmed with FTIR spectrum. The formation of colloidal polymer was also corroborated by a difference between glass transition temperatures of colloid film and corresponding homopolymers. Calorimetry measurements showed that the colloid is composed of random copolymer. The particle size distribution exhibits unimodal character, suggesting a high stability of the colloid polymer. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Chen  |D Lijun  |u School of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China  |4 aut 
700 1 |a Bao  |D Zhongbin  |u School of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China  |4 aut 
700 1 |a Fu  |D Zhengrong  |u School of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China  |4 aut 
700 1 |a Li  |D Wen  |u School of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China  |4 aut 
773 0 |t Colloid Journal  |d Pleiades Publishing  |g 77/3(2015-05-01), 374-381  |x 1061-933X  |q 77:3<374  |1 2015  |2 77  |o 10595 
856 4 0 |u https://doi.org/10.1134/S1061933X15030059  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1061933X15030059  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Chen  |D Lijun  |u School of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Bao  |D Zhongbin  |u School of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Fu  |D Zhengrong  |u School of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Li  |D Wen  |u School of Chemical Engineering, Zhejiang University of Technology, 310032, Hangzhou, China  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Colloid Journal  |d Pleiades Publishing  |g 77/3(2015-05-01), 374-381  |x 1061-933X  |q 77:3<374  |1 2015  |2 77  |o 10595