Formation kinetics of silver nanoparticles in reverse micelles. 1. Integral models and the relation between their parameters and microlevel processes

Verfasser / Beitragende:
[V. Kuz'min, A. Gadzaov, D. Tytik, S. Busev, A. Revina]
Ort, Verlag, Jahr:
2015
Enthalten in:
Colloid Journal, 77/4(2015-07-01), 458-472
Format:
Artikel (online)
ID: 605489785
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024 7 0 |a 10.1134/S1061933X15040110  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1061933X15040110 
245 0 0 |a Formation kinetics of silver nanoparticles in reverse micelles. 1. Integral models and the relation between their parameters and microlevel processes  |h [Elektronische Daten]  |c [V. Kuz'min, A. Gadzaov, D. Tytik, S. Busev, A. Revina] 
520 3 |a A method has been proposed for analysis of the evolution of optical absorption spectra measured during the synthesis of silver nanoparticles in reverse micelles. The Volterra "predator-prey” kinetic model has been employed as a basic one. The limiting solutions of this model have been found to be represented by controlled-growth curves (logistic and Gompertz models), parameters of which are determined by characteristics of microlevel processes. It has been shown that there are macrolevel-related physically interpreted parameters of the synthesis process. The tests of the models for the stability with respect to a phase shift (relaxation) have shown its interrelation with the parameters of the controlled-growth model. A correlation has been shown between the space-time characteristics (time and wavelength) of the system. The moments of the passages from one to another stage of the synthesis reaction have been determined. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Kuz'min  |D V.  |u Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, 119454, Moscow, Russia  |4 aut 
700 1 |a Gadzaov  |D A.  |u Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, 119454, Moscow, Russia  |4 aut 
700 1 |a Tytik  |D D.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia  |4 aut 
700 1 |a Busev  |D S.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia  |4 aut 
700 1 |a Revina  |D A.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia  |4 aut 
773 0 |t Colloid Journal  |d Pleiades Publishing  |g 77/4(2015-07-01), 458-472  |x 1061-933X  |q 77:4<458  |1 2015  |2 77  |o 10595 
856 4 0 |u https://doi.org/10.1134/S1061933X15040110  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
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950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1061933X15040110  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kuz'min  |D V.  |u Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, 119454, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Gadzaov  |D A.  |u Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, 119454, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Tytik  |D D.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Busev  |D S.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Revina  |D A.  |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Colloid Journal  |d Pleiades Publishing  |g 77/4(2015-07-01), 458-472  |x 1061-933X  |q 77:4<458  |1 2015  |2 77  |o 10595 
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